{(O-propionyl ethanimidato)phenylcarbene}pentacarbonylchromium⁽⁰⁾

Base Information

Chemical Name:{(O-propionyl ethanimidato)phenylcarbene}pentacarbonylchromium⁽⁰⁾
CAS No.:121809-15-2
Molecular Formula:C₁₇H₁₃CrNO₇
Molecular Weight:395.289
Hs Code.:

{(O-propionyl ethanimidato)phenylcarbene}pentacarbonylchromium<sup>(0)</sup>

Synonyms:

Suppliers and Price of {(O-propionyl ethanimidato)phenylcarbene}pentacarbonylchromium⁽⁰⁾

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {(O-propionyl ethanimidato)phenylcarbene}pentacarbonylchromium⁽⁰⁾

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {(O-propionyl ethanimidato)phenylcarbene}pentacarbonylchromium⁽⁰⁾

There total 1 articles about {(O-propionyl ethanimidato)phenylcarbene}pentacarbonylchromium⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

: 60-35-5
acetamide

: 15975-90-3
pentacarbonyl((phenyl)(tetramethylammonio)oxycarbene)chromium⁽⁰⁾

: 79-03-8
propionyl chloride

: 121809-15-2
{(O-propionyl ethanimidato)phenylcarbene}pentacarbonylchromium⁽⁰⁾

Guidance literature:: In dichloromethane; in a airlessware flask, under Ar, addn. of C2H5COCl to a soln. of (CO)5CrCO(Ph)NMe4 in dry CH2Cl2 ( at -23 °C), stirring 20 min, warming to -5 .degrre.C, addn. of CH3CONH2, stirring 30 min, slowly warming to room temp.; filtration (through Celite), evapn. (vac.), extn. (Et2O), filtration of the ether extracts (through Florosil), concg.(vac.), radial chromy. (silica gel, 5:1 petroleum ether/Et2O);
DOI:10.1021/om00111a015

Reference yield: 22.0%

: 121809-15-2
{(O-propionyl ethanimidato)phenylcarbene}pentacarbonylchromium⁽⁰⁾

: 622-29-7
N-Benzylidenemethylamine

: 121790-19-0
C₂₁H₂₂N₂O₃

: 121790-18-9
C₂₈H₂₉N₃O₃

Guidance literature:: In hexane; ethyl acetate; acetonitrile; stirring in CH3CN 24 h, then air oxidn. in 40% Et acetate/hexane; filtration, evapn. (vac.), radial chromy. (silica gel, 20%, followed by 30% and 40%, Et acetate/hexane) elem. anal.;
DOI:10.1021/om00111a015