11b,12c-diacetoxy-10-chloro-8,9-dimethoxy-2ξ-(4-methoxy-phenyl)-4,7,14-trimethyl-(6at,11bt)-6a,7,11b,12-tetrahydro-4,12a-azaethano-[1,3,5]dithiazepino[5',4':1,5]pyrrolo[2,3-b]indole-5,13-dione

Base Information

• Chemical Name: 11b,12c-diacetoxy-10-chloro-8,9-dimethoxy-2ξ-(4-methoxy-phenyl)-4,7,14-trimethyl-(6at,11bt)-6a,7,11b,12-tetrahydro-4,12a-azaethano-[1,3,5]dithiazepino[5',4':1,5]pyrrolo[2,3-b]indole-5,13-dione
• CAS No.: 50801-20-2
• Molecular Formula: C₃₀H₃₂ClN₃O₉S₂
• Molecular Weight: 678.184

Synonyms:

Chemical Property of 11b,12c-diacetoxy-10-chloro-8,9-dimethoxy-2ξ-(4-methoxy-phenyl)-4,7,14-trimethyl-(6at,11bt)-6a,7,11b,12-tetrahydro-4,12a-azaethano-[1,3,5]dithiazepino[5',4':1,5]pyrrolo[2,3-b]indole-5,13-dione

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 11b,12c-diacetoxy-10-chloro-8,9-dimethoxy-2ξ-(4-methoxy-phenyl)-4,7,14-trimethyl-(6at,11bt)-6a,7,11b,12-tetrahydro-4,12a-azaethano-[1,3,5]dithiazepino[5',4':1,5]pyrrolo[2,3-b]indole-5,13-dione

There total 2 articles about 11b,12c-diacetoxy-10-chloro-8,9-dimethoxy-2ξ-(4-methoxy-phenyl)-4,7,14-trimethyl-(6at,11bt)-6a,7,11b,12-tetrahydro-4,12a-azaethano-[1,3,5]dithiazepino[5',4':1,5]pyrrolo[2,3-b]indole-5,13-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[bis(acetoxy)iodo]benzene (3240-34-4) + (1RS)-1-[(RS)-acetoxy-(5-chloro-6,7-dimethoxy-1-methyl-indol-3-yl)-methyl]-3ξ-(4-methoxy-phenyl)-5,6-dimethyl-2,4-dithia-6,8-diaza-bicyclo[3.2.2]nonane-7,9-dione (50801-19-9) → 11b,12c-diacetoxy-10-chloro-8,9-dimethoxy-2ξ-(4-methoxy-phenyl)-4,7,14-trimethyl-(6at,11bt)-6a,7,11b,12-tetrahydro-4,12a-azaethano-[1,3,5]dithiazepino[5',4':1,5]pyrrolo[2,3-b]indole-5,13-dione (50801-20-2)

Guidance literature:

With dimethylsulfide; In acetonitrile;

DOI:10.1021/ja00800a079

Reference yield:

acetic anhydride (108-24-7) + 4-methoxy-benzaldehyde (123-11-5) + sporidesmin A (1456-55-9,6781-30-2,50763-61-6) → (4R)-11b,12c-diacetoxy-10-chloro-8,9-dimethoxy-2ξ-(4-methoxy-phenyl)-4,7,14-trimethyl-(6at,11bt)-6a,7,11b,12-tetrahydro-4,12a-azaethano-[1,3,5]dithiazepino[5',4':1,5]pyrrolo[2,3-b]indole-5,13-dione (50801-20-2)

Guidance literature:

Multistep reaction; (i) NaBH₄, MeOH, (ii) /BRN= 471382/, BF₃-Et₂O, CH₂Cl₂, (iii) /BRN= 385737/, Py;

DOI:10.1021/ja00800a079

Reference yield:

(4R)-11b,12c-diacetoxy-10-chloro-8,9-dimethoxy-2ξ-(4-methoxy-phenyl)-4,7,14-trimethyl-(6at,11bt)-6a,7,11b,12-tetrahydro-4,12a-azaethano-[1,3,5]dithiazepino[5',4':1,5]pyrrolo[2,3-b]indole-5,13-dione (50801-20-2) → sporidesmin A (1456-55-9,6781-30-2,50763-61-6)

Guidance literature:

Multistep reaction; (i) NaOH, aq. MeOH, (ii) MCPBA, CH₂Cl₂, (iii) BF₃-Et₂O;

DOI:10.1021/ja00800a079

upstream raw materials:

acetic anhydride

4-methoxy-benzaldehyde

sporidesmin A

[bis(acetoxy)iodo]benzene

Downstream raw materials:

sporidesmin A

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 50801-20-2 11b,12c-diacetoxy-10-chloro-8,9-dimethoxy-2ξ-(4-methoxy-phenyl)-4,7,14-trimethyl-(6at,11bt)-6a,7,11b,12-tetrahydro-4,12a-azaethano-[1,3,5]dithiazepino[5',4':1,5]pyrrolo[2,3-b]indole-5,13-dione

Send

Send

Metric Ton KG G Pound L ML

Send

Send