1-{(2,3,5-tri-O-benzoyl-D-ribofuranosyl)methyl}-1,2-dicarba-closo-dodecaborane

Base Information

Chemical Name:1-{(2,3,5-tri-O-benzoyl-D-ribofuranosyl)methyl}-1,2-dicarba-closo-dodecaborane
CAS No.:117162-37-5
Molecular Formula:C₂₉H₃₄B₁₀O₈
Molecular Weight:618.694
Hs Code.:

Synonyms:

Suppliers and Price of 1-{(2,3,5-tri-O-benzoyl-D-ribofuranosyl)methyl}-1,2-dicarba-closo-dodecaborane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-{(2,3,5-tri-O-benzoyl-D-ribofuranosyl)methyl}-1,2-dicarba-closo-dodecaborane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-{(2,3,5-tri-O-benzoyl-D-ribofuranosyl)methyl}-1,2-dicarba-closo-dodecaborane

There total 1 articles about 1-{(2,3,5-tri-O-benzoyl-D-ribofuranosyl)methyl}-1,2-dicarba-closo-dodecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 6974-32-9
1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose

: 19610-34-5
(1'-hydroxymethyl)-1,2-dicarba-closo-dodecaborane

: 7646-78-8
tin(IV) chloride

: 117162-37-5
1-{(2,3,5-tri-O-benzoyl-D-ribofuranosyl)methyl}-1,2-dicarba-closo-dodecaborane

Guidance literature:: In dichloromethane; (Ar); chilling the soln. of 1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose to 5°C; stirring this soln. at room temp. for 10 min after addn. of SnCl4; then addn. of the carborane and stirring of the mixt. for addnl. 2 h at room temp.;; diln. with CH2Cl2; pouring of the soln. in a separatory funnel with satd. aq. Na(HCO3)2; washing of the aq. layer with CH2Cl2; drying of the organic portions over MgSO4; concn.; chromy. (Kieselgel, ethyl acetate/hexane); solvent removal; elem. anal.;;
DOI:10.1021/om00102a015