[tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH₂Cl₂*water

Base Information

• Chemical Name: [tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH₂Cl₂*water
• CAS No.: 1207761-84-9
• Molecular Formula: CH₂Cl₂*C₁₈H₁₄N₄O₂Os*C₂₄H₂₀P*H₂O
• Molecular Weight: 950.879
• Mol file: 1207761-84-9.mol

Synonyms:

Chemical Property of [tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH₂Cl₂*water

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH₂Cl₂*water

There total 1 articles about [tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH₂Cl₂*water which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

potassium cyanide + dichloromethane (75-09-2) + Os(III)Cl(PPh3)(N,N'-ethylenebis(salicylideneaminato)) (1207761-88-3) + water (7732-18-5) + tetraphenyl phosphonium chloride (2001-45-8) → [tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH2Cl2*water (1207761-84-9)

Guidance literature:

In ethanol; refluxing mixt. of osmium compd. and KCN in ethanol for 4 h; evapn., dissolving in water, addn. of phosphonium deriv., collecting ppt., washing with water, drying in vac., recrystn. by layering diethyl ether over CH2Cl2 soln. at room temp. for 1 wk, elem. anal.;

DOI:10.1021/ic9020178

Reference yield: 57.0%

[Cu(N,N',N''-trimethyl-1,4,7-triazacyclononane)(H2O)2](ClO4)2 + [tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH2Cl2*water (1207761-84-9) → [Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))][Cu(1,4,7-trimethyl-1,4,7-triazacyclononane)]perchlorate

Guidance literature:

In methanol; N,N-dimethyl-formamide; slow interdiffusion of methanolic soln. of osmium compd. and DMF soln. of copper compd. in H tube, keeping for 3 d at room temp.; isolation of crystals, elem. anal.;

DOI:10.1021/ic9020178

Reference yield: 21.0%

methanol (67-56-1) + [Cu(N,N',N''-trimethyl-1,4,7-triazacyclononane)(H2O)2](ClO4)2 + [tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH2Cl2*water (1207761-84-9) → [Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]2[Cu(1,4,7-trimethyl-1,4,7-triazacyclononane)]*methanol

Guidance literature:

In methanol; N,N-dimethyl-formamide; layering methanolic soln. of osmium compd. over DMF soln. of copper compd., keeping for 1 wk at room temp.; isolation of crystals, elem. anal.;

DOI:10.1021/ic9020178

upstream raw materials:

dichloromethane

Os(III)Cl(PPh₃)(N,N'-ethylenebis(salicylideneaminato))

water

tetraphenyl phosphonium chloride