bis(1,3-bis(diphenylphosphino)propane)rhodium formate

Base Information

• Chemical Name: bis(1,3-bis(diphenylphosphino)propane)rhodium formate
• CAS No.: 150904-96-4
• Molecular Formula: CHO₂*C₅₄H₅₂P₄Rh
• Molecular Weight: 972.825
• Mol file: 150904-96-4.mol

Synonyms:

Chemical Property of bis(1,3-bis(diphenylphosphino)propane)rhodium formate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis(1,3-bis(diphenylphosphino)propane)rhodium formate

There total 5 articles about bis(1,3-bis(diphenylphosphino)propane)rhodium formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Rh(H)(Ph2P(CH2)3PPh2)2 (70196-25-7) → bis(1,3-bis(diphenylphosphino)propane)rhodium formate (150904-96-4)

Guidance literature:

With carbon dioxide; In dimethylsulfoxide-d6; reaction of Rh-complex with 1 atm CO2 at room temp. for 30 min; monitored by (1)H NMR (quantitative formation);

Reference yield:

formic acid (64-18-6) + Rh(H)(Ph2P(CH2)3PPh2)2 (70196-25-7) → bis(1,3-bis(diphenylphosphino)propane)rhodium formate (150904-96-4)

Guidance literature:

In dimethyl sulfoxide; Rh-complex reacted with HCO2H at 20, 30, 35°C in DMSO; monitored by UV/VIS; Kinetics;

DOI:10.1002/zaac.200800352

Reference yield:

bis[1,3-bis(diphenylphosphino)propane]rhodium chloride (71264-67-0,53450-82-1) + sodium formate (141-53-7) → bis(1,3-bis(diphenylphosphino)propane)rhodium formate (150904-96-4)

Guidance literature:

In dimethyl sulfoxide; Rh-complex reacted with NaHCO2 in DMSO at 35°C; Kinetics;

DOI:10.1002/zaac.200800352

upstream raw materials:

formic acid

1,3-bis-(diphenylphosphino)propane

Rh(H)(Ph₂P(CH₂)3PPh₂)2

bis[1,3-bis(diphenylphosphino)propane]rhodium chloride