[Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4)

Base Information

• Chemical Name: [Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4)
• CAS No.: 75812-17-8
• Molecular Formula: C₂₀H₃₇Cu₂N₄O₃*C₂₄H₂₀B
• Molecular Weight: 827.865
• Mol file: 75812-17-8.mol

Synonyms:

Chemical Property of [Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4)

There total 6 articles about [Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

copper(l) iodide (7681-65-4) + N,N,N,N,-tetramethylethylenediamine (110-18-9) + sodium tetraphenyl borate (143-66-8) + thallium benzoate (5630-31-9) → [Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4) (81770-59-4,75812-17-8)

Guidance literature:

With CO; In dichloromethane; byproducts: TlI, NaO2CC6H5; suspn. of CuI was stirred for 30 min under CO; tmed was added, stirringfor 20 min; addn. of TlOBz; stirring under CO for 30 min; filtration, addn. of NaBPh4 to filtrate over 10 min; react. for 30 min; filtration, evapn., washing with pentane; elem. anal.;

DOI:10.1021/om00072a012

Reference yield: 89.5%

{Cu(μ-O2CC6H5)}4 + N,N,N,N,-tetramethylethylenediamine (110-18-9) + sodium tetraphenyl borate (143-66-8) → [Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4) (81770-59-4,75812-17-8)

Guidance literature:

With CO; In methanol; byproducts: CO; complex was treated with CO in MeOH; formed solid dissolved upon addn. of tmen; filtration (CO), addn. to soln. of NaBPh4; formed white solid converted into yellow solid; filtration (N2), drying; elem. anal.;

DOI:10.1021/ja00379a009

Reference yield:

benzoic acid (65-85-0,8013-63-6) → [Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4) (81770-59-4,75812-17-8)

Guidance literature:

Multi-step reaction with 2 steps

1: benzene

2: CO / dichloromethane

With CO; In dichloromethane; benzene;

DOI:10.1021/om00072a012

upstream raw materials:

sodium benzoate

CuN(CH₃)2CH₂CH₂(CH₃)2N(CO)HOCH₃⁽¹⁺⁾*B(C₆H₅)4^(1-)

copper(l) iodide

N,N,N,N,-tetramethylethylenediamine