5630-31-9

Basic information

• Product Name: Benzoic acid, thallium(1+) salt
• CAS NO: 5630-31-9
• Molecular Formula: C7H6O2.Tl
• Molecular Weight: 325.499
• Mol File: 5630-31-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid, thallium(1+) salt(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, thallium(1+) salt(5630-31-9)
• EPA Substance Registry System: Benzoic acid, thallium(1+) salt(5630-31-9)

Safety Data

• Hazardous Substances Data: 5630-31-9(Hazardous Substances Data)

Upstream product

• 94-36-0 dibenzoyl peroxide 
• 563-68-8 thallium(I) acetate 
• 65-85-0 benzoic acid 

Downstream Products

• 2819-08-1 benzoyl acetate 
• 1068653-13-3 [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(nitrosyl)(benzoato-κ1O)](BF4) 
• 1068652-98-1 [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(acetonitrile)(benzoate-κ1O)] 
• 791601-93-9 [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(benzoate-κ2O,O')] 
• 358750-74-0 di[(μ-benzoato-O,O')bis(η(5)-methylcyclopentadienyl)ytterbium(III)] 
• 83312-24-7 (NH₂CH₂CH₂N(CH₃)2)2Cu₂(CO)(CO₂C₆H₅)⁽¹⁺⁾*C₆H₅CO₂^(1-) = [Cu₂(NH₂CH₂CH₂N(CH₃)2)2CO(CO₂C₆H₅)]C₆H₅CO₂ 
• 83312-00-9 ((CH₂NH₂)2)2Cu₂(CO)(CO₂C₆H₅)⁽¹⁺⁾*C₆H₅CO₂^(1-) = [Cu₂((CH₂NH₂)2)2CO(CO₂C₆H₅)]C₆H₅CO₂ 
• 83376-24-3 ((CH₂N(CH₃)2)2)2Cu₂(CO)(CO₂C₆H₅)⁽¹⁺⁾*C₆H₅CO₂^(1-) = [Cu₂((CH₂N(CH₃)2)2)2CO(CO₂C₆H₅)]C₆H₅CO₂ 
• 81770-59-4 [Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4) 
• 83312-22-5 ((CH₂NH(CH₃))2)2Cu₂(CO)(CO₂C₆H₅)⁽¹⁺⁾*C₆H₅CO₂^(1-) = [Cu₂((CH₂NH(CH₃))2)2CO(CO₂C₆H₅)]C₆H₅CO₂ 
• 43084-80-6 C₂₇H₃₆O₂ 
• 43084-79-3 17-Benzoyloxy-phyllocladen-⁽¹⁵⁾ 
• 54826-38-9 1-Benzoyloxy-1-phenyl-2-iodpropan 
• 54826-54-9 2-Iod-1-methyl-1-phenylethylbenzoat 

Relevant articles and documents

Ruthenium(II) complexes bearing carboxylato and 2-oxocarboxylato ligands

The syntheses of ruthenium(II) acetato and benzoato complexes [Ru(bdmpza/(O2CCH3)(PPh3)] (6) and [Ru(bdmpza/)-(O2CPh)(PPh3)] (7) [bdmpza = bis(3,5-dimethylpyrazol-1-yl)-acetate] are reported. The complexes 6 and 7 are synthesized in high yield from [Ru(bdmpza)Cl(PPh3)2] (1) and thallium acetate (2) or thallium benzoate (3). In a similar substitution reaction a benzoylformate complex [Ru(bdmpza){O2C-C(O)Ph}(PPh 3)] (8) is obtained from 1 and thallium benzoylformate (4). Reaction of 6 or 7 with benzoylformic acid also yields 8. In analogous reactions several 2-oxocarboxylato ruthenium(II) complexes [Ru(bdmpza){O2CC(O)R} (PPh3)] (9 R = CH2CH2CO2H, 10: R = Me, 11: R = Et) can be obtained. The low-spin ruthenium(II) complexes 8 to 11 exhibit a purple or brownish-red colour caused by MLCT transitions and thus a HOMO-LUMO gap which is almost identical to that of high-spin 2-oxoglutarate dependent iron oxygenases. 6 crystallises as a water adduct, 6·H 2O and 8 forms an acetonitrile adduct 12, Crystal structures of the water adduct 6.H2O and 8 were obtained. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.