Mo2Cl4(μ-bis(diphenylphosphino)methane)2

Base Information

Chemical Name:Mo2Cl4(μ-bis(diphenylphosphino)methane)2
CAS No.:69120-54-3
Molecular Formula:C₅₀H₄₄Cl₄Mo₂P₄
Molecular Weight:1102.49
Hs Code.:

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Chemical Property of Mo2Cl4(μ-bis(diphenylphosphino)methane)2

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Technology Process of Mo2Cl4(μ-bis(diphenylphosphino)methane)2

There total 4 articles about Mo2Cl4(μ-bis(diphenylphosphino)methane)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: Mo₂Cl₄((C₆H₅)2PCH₂P(C₆H₅)2)2*2C₄H₈O

: 882-33-7
diphenyldisulfane

: 69120-54-3,64508-35-6
Mo2Cl4(μ-bis(diphenylphosphino)methane)2

: Mo2(μ-SPh)2Cl4(bis(diphenylphosphino)methane)2

Guidance literature:: In dichloromethane; Mo2-complex and PhSSPh were refluxed in CH2Cl2 under inert atmosphere for 13 h; starting complex was recovered in 88% yield, thus no reaction had occured; cooled at -20°C for 3 d, crystals collected;
DOI:10.1021/ja00311a036

Reference yield: 58.0%

: 75-77-4
chloro-trimethyl-silane

: 116791-07-2
Mo₂(O₂CCH₃)2Cl₂(dppee)

: 2071-20-7
bis-diphenylphosphinomethane

: 69120-54-3,64508-35-6
Mo2Cl4(μ-bis(diphenylphosphino)methane)2

Guidance literature:: In tetrahydrofuran; a mixture of Mo2(O2CCH3)2Cl2(dppee), dppm, THF and Me3SiCl was stirred at room temp. for 20 h, a green solid was filtered off;; washed with with THF, hexane and diethyl ether, dried; elemental analysis;;
DOI:10.1016/S0277-5387(00)81224-3

Reference yield: 55.0%

: [Mo₂Cl₆(tetrahydrofuran)3]

: 109-89-7
diethylamine

: 2071-20-7
bis-diphenylphosphinomethane

: 69120-54-3,64508-35-6
Mo2Cl4(μ-bis(diphenylphosphino)methane)2

Guidance literature:: With Na/Hg; In tetrahydrofuran; hexane; byproducts: NaCl; inert atmosphere; addn. of excess NHEt2 and 2 equiv. of 0.4% NaHg to Mo-complex soln. (in THF, -78°C), warming to room temp., stirring for 24 h, addn. of C6H6, filtration off of NaCl, addn. of excess phosphine(in hexanes), stirring for 90 min; concn., filtration, washing (C6H6), drying (vac.), dissoln. in hexanes, crystn. on layering with CH2Cl2;