(Z)-1-trimethylsilyl-1-trimethylstannyl-2-phenylethene

Base Information

Chemical Name:(Z)-1-trimethylsilyl-1-trimethylstannyl-2-phenylethene
CAS No.:87673-47-0
Molecular Formula:C₁₄H₂₄SiSn
Molecular Weight:339.14
Hs Code.:

Synonyms:

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Chemical Property of (Z)-1-trimethylsilyl-1-trimethylstannyl-2-phenylethene

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Technology Process of (Z)-1-trimethylsilyl-1-trimethylstannyl-2-phenylethene

There total 6 articles about (Z)-1-trimethylsilyl-1-trimethylstannyl-2-phenylethene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: triethylphosphite copper(I) iodide complex

: 1066-45-1
trimethyltin(IV)chloride

: 917-54-4
methyllithium

: 1191-15-7
diisobutylaluminium hydride

: 2170-06-1
1-Phenyl-2-(trimethylsilyl)acetylene

: 19372-00-0
1-(trimethylsilyl)-2-phenylethene

: 87673-47-0,97537-92-3
(Z)-1-trimethylsilyl-1-trimethylstannyl-2-phenylethene

Guidance literature:: In tetrahydrofuran; diethyl ether; pentane; Ar atmosphere, addn. of (C4H9)2AlH to Si compound (in pentane, 16 h, room temp.), evapn., cooling (-78°C, Et2O), warming (0°C), addn. MeLi (Et2O, 2 h, 20°C), addn. Cu complex and Me3SnCl (THF, -78°C, 1.5 h), extn. (Et2O); washing (water), drying, addn. of hexane, filtration, chromy. (silica gel, hexane); elem. anal.;

Reference yield: 51.0%

: 120-94-5
1-Methylpyrrolidine

: triethylphosphite copper(I) iodide complex

: 917-54-4
methyllithium

: 1191-15-7
diisobutylaluminium hydride

: 2170-06-1
1-Phenyl-2-(trimethylsilyl)acetylene

: 87673-47-0,97537-92-3
(E)-1-trimethylsilyl-1-trimethylstannyl-2-phenylethene

: 19319-11-0
(Z)-1-phenyl-2-(trimethylsilyl)ethylene

Guidance literature:: In tetrahydrofuran; diethyl ether; n-heptane; Ar atmosphere, addn. of (C4H9)2AlH to pyrrolidine, Si compd. addn. (55°C), evapn., cooling (-78°C, Et2O), warming (0°C), MeLi addn. (Et2O, 20°C), addn. Cu complex and Me3SnCl-further educt (THF, -78°C), extn. (Et2O); washing (water), drying, addn. of hexane, filtration, chromy. (silica gel, hexane); elem. anal.;

Reference yield: 45.0%

: 78338-47-3
C₆H₅CHC(Sn(CH₃)3)2

: 16029-98-4
trimethylsilyl iodide

: 87673-47-0,97537-92-3
(Z)-1-trimethylsilyl-1-trimethylstannyl-2-phenylethene

Guidance literature:: With methyllithium; In tetrahydrofuran; byproducts: tetramethyltin, PhCH=CHSnMe3; MeLi in THF was added slowly with stirring at -78°C under Ar to a soln. of PhCH=C(SnMe3)2 in THF, stirred for 1 h, Me3SiI was added at -78°C, mixt. was kept 1 h at -78°C, warmed to room temp., heated for 15 min under reflux; volatiles were removed at the water pump, residue was subjected to a fractional distn.; elem. anal.;
DOI:10.1016/0022-328X(83)80057-6