4,4',4''-(1-Vinyl-2-ylidene)trianisole

Base Information

• Chemical Name: 4,4',4''-(1-Vinyl-2-ylidene)trianisole
• CAS No.: 7109-27-5
• Molecular Formula: C23H22 O3
• Molecular Weight: 346.426
• European Community (EC) Number: 230-413-3
• NSC Number: 36377
• DSSTox Substance ID: DTXSID80221312
• Nikkaji Number: J227.380B
• ChEMBL ID: CHEMBL1598215
• Mol file: 7109-27-5.mol

Synonyms:4,4',4''-(1-Vinyl-2-ylidene)trianisole;7109-27-5;EINECS 230-413-3;1,1,2-Tris(4-methoxyphenyl)ethene;1,1',1''-ethene-1,1,2-triyltris(4-methoxybenzene);NSC36377;Oprea1_036523;MLS000533478;C12H20Cl2N4O6S2;SCHEMBL9839256;CHEMBL1598215;DTXSID80221312;HMS2167P10;HMS3312M06;NSC 36377;NSC-36377;STK955272;1,1,2-Tris(4-methoxyphenyl) ethene;AKOS003304059;C12-H20-Cl2-N4-O6-S2;NCGC00245615-01;SMR000140915;4,4',4''-(ethene-1,1,2-triyl)tris(methoxybenzene);1,1',1''-(1,1,2-ethenetriyl)tris(4-methoxybenzene);Benzene, 1,1',1''-(1-ethenyl-2-ylidene)tris(4-methoxy-

Chemical Property of 4,4',4''-(1-Vinyl-2-ylidene)trianisole

Chemical Property:

• Boiling Point: 489.5oC at 760 mmHg
• Flash Point: 168oC
• PSA: 27.69000
• Density: 1.113g/cm3
• LogP: 5.30130
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 346.15689456
• Heavy Atom Count: 26
• Complexity: 397

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C=C(C2=CC=C(C=C2)OC)C3=CC=C(C=C3)OC

Technology Process of 4,4',4''-(1-Vinyl-2-ylidene)trianisole

There total 35 articles about 4,4',4''-(1-Vinyl-2-ylidene)trianisole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

iodo-tris-(4-methoxy-phenyl)-ethene (114795-34-5) → 1,1,2-tris(4-methoxyphenyl)ethene (7109-27-5)

Guidance literature:

With lithium aluminium tetrahydride; nickel dichloride; In tetrahydrofuran; < 0 deg C;

Reference yield: 95.0%

chlorotrianisene (569-57-3) → 1,1,2-tris(4-methoxyphenyl)ethene (7109-27-5)

Guidance literature:

With lithium aluminium tetrahydride; nickel dichloride; In tetrahydrofuran; < 0 deg C;

Reference yield: 95.0%

1-bromo-1,2,2-tris(p-methoxyphenyl)ethene (25354-46-5) → 1,1,2-tris(4-methoxyphenyl)ethene (7109-27-5)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; < 0 deg C;

upstream raw materials:

4'-methoxy-2,2-bis(p-methoxyphenyl)acetophenone

1,1,2-tris-(4-methoxy-phenyl)-ethanol

chloroacetic acid ethyl ester

4-methoxyphenyl magnesium bromide

Downstream raw materials:

chlorotrianisene

1-bromo-1,2,2-tris(p-methoxyphenyl)ethene

1,1,2-tris(4-methoxyphenyl)ethane

4,4',4''-ethenetriyl-tri-phenol

Refernces

• 1、 Wu, Ke,Sun, Nan,Hu, Baoxiang,Shen, Zhenlu,Jin, Liqun,Hu, Xinquan. "Geometry-Constrained Iminopyridyl Palladium-Catalyzed Hydroarylation of Alkynes to Prepare Tri-substituted Alkenes Using Alcohol as Reductant". supporting information. p. 3038 - 3043. Retrieved 2018/08/01.
• 2、 -. "REAGENT FOR ENHANCING GENERATION OF CHEMICAL SPECIES". . . Retrieved 2016/06/13.