cis-[PtBr₂(PPh₃)2]

Base Information

• Chemical Name: cis-[PtBr₂(PPh₃)2]
• CAS No.: 26026-46-0
• Molecular Formula: C₃₆H₃₀Br₂P₂Pt
• Molecular Weight: 879.47
• Mol file: 26026-46-0.mol

Synonyms:

Chemical Property of cis-[PtBr₂(PPh₃)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[PtBr₂(PPh₃)2]

There total 33 articles about cis-[PtBr₂(PPh₃)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1) + Acetyl bromide (506-96-7) → cis-[PtBr2(PPh3)2] (26026-46-0,18517-48-1,16242-58-3) + acetyl chloride (75-36-5)

Guidance literature:

In dichloromethane; at 20 - 25 ℃; for 0.5h; Glovebox;

DOI:10.1021/om400157a

Reference yield: 99.0%

[platinum(II)(bromide)2(acetonitrile)2] (13869-36-8) + triphenylphosphine (603-35-0) → trans-dibromobis(triphenylphosphine)platinum (16242-58-3,18517-48-1,26026-46-0)

Guidance literature:

In nitromethane; PPh3 (0.19 mmol) added to soln. of Pt complex (0.099 mmol), stirred at 50°C for 30 min; ppt. filtered off, washed with iPr2O, dried in vac.; elem. anal.;

DOI:10.1016/j.ica.2010.07.002

Reference yield: 90.0%

potassium tetrachloroplatinate(II) (10025-99-7) + triphenylphosphine (603-35-0) + potassium bromide (7558-02-3,7758-02-3) → cis-[PtBr2(PPh3)2] (26026-46-0,18517-48-1,16242-58-3)

Guidance literature:

In ethanol; water; solid KBr was added to aq. soln. of Pt complex; soln. was added to soln.of PPh3 in EtOH; stirred at room temp. for 4 h; cooled; filtered; elem. anal.;

DOI:10.1021/ic901510m

upstream raw materials:

[platinum(II)(bromide)2(acetonitrile)2]

triphenylphosphine

cis-dichlorobis(triphenylphosphine)platinum(II)

tetrakis(triphenylphosphine)platinum

Downstream raw materials:

((C₆H₅)3P)2PtBrF

(bicyclo[2.2.1]hept-2-ene)bis(triphenylphosphine)platinum

PtBr(CH₃C₅H₄N)(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=(PtBr(CH₃C₅H₄N)(P(C₆H₅)3)2)BF₄

cis-bis(triphenylphosphine)bromo(3-bromobicyclo[2.2.1]hept-2-en-2-yl)platinum(II)