(tris(2-diphenylphosphinoethyl)phosphine)RhSeH

Base Information

Chemical Name:(tris(2-diphenylphosphinoethyl)phosphine)RhSeH
CAS No.:116399-24-7
Molecular Formula:C₄₂H₄₃P₄RhSe
Molecular Weight:853.564
Hs Code.:

Synonyms:

Suppliers and Price of (tris(2-diphenylphosphinoethyl)phosphine)RhSeH

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (tris(2-diphenylphosphinoethyl)phosphine)RhSeH

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (tris(2-diphenylphosphinoethyl)phosphine)RhSeH

There total 1 articles about (tris(2-diphenylphosphinoethyl)phosphine)RhSeH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 7782-49-2
selenium

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 14104-20-2
silver tetrafluoroborate

: 23582-03-8
tris(2-diphenylphosphinoethyl)phosphine

: 116399-24-7
(tris(2-diphenylphosphinoethyl)phosphine)RhSeH

Guidance literature:: With sodium tetrahydroborate; In tetrahydrofuran; ethanol; dichloromethane; THF soln. of Rh compd. treated with stoichiometric amt. of AgBF4, then filtered; a soln. of phosphine in CH2Cl2 and a clear ethanol soln. obtained by reduction of the chalcogen with NaBH4 were then added,; reducing of the volume of the solvent under N2;compd. gave satisfactory elem. anal.;
DOI:10.1016/S0022-328X(00)99821-8

Reference yield: 85.0%

: 116399-24-7
(tris(2-diphenylphosphinoethyl)phosphine)RhSeH

: 1493-13-6
trifluorormethanesulfonic acid

: (tris(2-diphenylphosphinoethyl)phosphine)RhSeH(CF₃SO₃)

Guidance literature:: In tetrahydrofuran; anhydrous THF,; isolated after addn. of benzene, characterization by IR and (1)H, (31)P NMR;
DOI:10.1016/S0022-328X(00)99821-8

Reference yield: 80.0%

: 116399-24-7
(tris(2-diphenylphosphinoethyl)phosphine)RhSeH

: 1493-13-6
trifluorormethanesulfonic acid

: 116363-54-3
{(tris(2-(diphenylphosphino)ethyl)phosphine)Rh(H)(SeH)}CF₃SO₃

Guidance literature:: In tetrahydrofuran; under N2; acid added to suspension of complex at 0°C with stirring, dissolution within a few min,; addn. of large excess benzene, filtered (closed system), washed (benzene, petroleum ether), dried under N2; elem. anal.;