1,1-bis(bis(trimethylsilyl)methyl)-3-phenyl-1,4,5,6-tetrahydrobenzo[c][1,2]oxagermole

Base Information

• Chemical Name: 1,1-bis(bis(trimethylsilyl)methyl)-3-phenyl-1,4,5,6-tetrahydrobenzo[c][1,2]oxagermole
• CAS No.: 618386-74-6
• Molecular Formula: C₂₇H₅₀GeOSi₄
• Molecular Weight: 575.625
• Mol file: 618386-74-6.mol

Synonyms:

Chemical Property of 1,1-bis(bis(trimethylsilyl)methyl)-3-phenyl-1,4,5,6-tetrahydrobenzo[c][1,2]oxagermole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1-bis(bis(trimethylsilyl)methyl)-3-phenyl-1,4,5,6-tetrahydrobenzo[c][1,2]oxagermole

There total 1 articles about 1,1-bis(bis(trimethylsilyl)methyl)-3-phenyl-1,4,5,6-tetrahydrobenzo[c][1,2]oxagermole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

benzophenone (119-61-9) + hydrogen (1333-74-0) + bis[bis(trimethylsilyl)methyl]germanium(II) (60111-69-5) → 1,1-bis(bis(trimethylsilyl)methyl)-3-phenyl-1,4,5,6-tetrahydrobenzo[c][1,2]oxagermole (618386-74-6)

Guidance literature:

Wilkinson's catalyst; In benzene; High Pressure; under Ar; in glass bomb; Ge compd. and benzophenone (molar ratio 1:1) reacted in benzene for 2 min; Rh complex (8 mol%) added; frozen (-78°C); evacuated; filled with H2 (3 atm); thawed and stirred at room temp. for 16 h; volatiles removed in vac.; dissolved in hexane; filtered through Celite;solvent removed from filtrate; recrystd. from propionitrile; elem. anal .;

DOI:10.1021/om034025t

upstream raw materials:

benzophenone

hydrogen

bis[bis(trimethylsilyl)methyl]germanium(II)