diphenyltetrabenzoporphinatozinc

Base Information

• Chemical Name: diphenyltetrabenzoporphinatozinc
• CAS No.: 132040-17-6
• Molecular Formula: C₄₈H₂₈N₄Zn
• Molecular Weight: 726.167
• Mol file: 132040-17-6.mol

Synonyms:

Chemical Property of diphenyltetrabenzoporphinatozinc

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenyltetrabenzoporphinatozinc

There total 4 articles about diphenyltetrabenzoporphinatozinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

phenylacetic acid (103-82-2) + zinc diacetate (557-34-6) + 3,3-[1-(1-oxo-1H-isoindol-3-yl)methylene]-2,3-dihydro-1H-isoindol-1-one → diphenyltetrabenzoporphinatozinc (132040-17-6)

Guidance literature:

With sodium hydroxide; In melt; Na-phenylacetate (from NaOH and the acid), Zn-compd., and N-compd. mixing and melting (340°C, 1 h), melt cooling and grinding; product extracting (benzene) and sepn. by chromy. (alumina/benzene), eluent evapn., recrystn. (methanol); elem. anal.;

Reference yield: 3.0%

potassium phtalimide (1074-82-4) + zinc(II) phenylacetate → zinc(II) complex with trans-diphenyltetrabenzoporphine (132040-17-6) + meso-diphenyltetrabenzoporphyrin zinc (132040-16-5) + zinc(II) complex with triphenyltetrabenzoporphine (120389-74-4) + zinc(II) tetraphenyltetrabenzoporphinate (80529-82-4)

Guidance literature:

In solid; well ground mixt. of potassium phthalimide salt and Zn(OCH2Ph)2 was heated at 360°C for 1 h under N2; extd. with hot dioxane and purified by column chromy. and PTLC on Al2O3 (benzene-hexane), septd. on Al2O3 (benzene-hexane-THF); isomers of meso-diphenyltetrabenzoporphinato zinc (2%) not septd.; contaminated with benzyl adducts (3D-HLPC and FD-MS data);

DOI:10.1016/S0020-1693(00)87937-2

Reference yield: 0.4%

zinc diacetate (557-34-6) + 3-benzylidenephthalimidine (5194-47-8) → zinc(II) complex with monophenyltetrabenzoporphine (120389-73-3) + zinc(II) complex with trans-diphenyltetrabenzoporphine (132040-17-6) + meso-diphenyltetrabenzoporphyrin zinc (132040-16-5) + zinc(II) complex with triphenyltetrabenzoporphine (120389-74-4) + zinc(II) tetraphenyltetrabenzoporphinate (80529-82-4)

Guidance literature:

A mixt. of benzylidenephthalimidine (BPI) and zinc acetate is heated at 360°C for 1 h under N2.; Product is washed with hot water and extd. with THF, evapn. gaves a residue, which is chromd. first (Al2O3-column, dioxane), purification by TLC on Al2O3, using a sovent mixture of benzene/hexane/THF (10:10:1) gives five major fractions.;

DOI:10.1016/S0020-1693(00)85087-2

upstream raw materials:

potassium phtalimide

zinc diacetate

3-benzylidenephthalimidine

phenylacetic acid

Downstream raw materials:

diphenyltetrabenzoporphinatonickel(II)

diphenyltetrabenzoporphinatocobalt(II)