zinc(II) complex with monophenyltetrabenzoporphine

Base Information

• Chemical Name: zinc(II) complex with monophenyltetrabenzoporphine
• CAS No.: 120389-73-3
• Molecular Formula: C₄₂H₂₄N₄Zn
• Molecular Weight: 650.069
• Mol file: 120389-73-3.mol

Synonyms:

Chemical Property of zinc(II) complex with monophenyltetrabenzoporphine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zinc(II) complex with monophenyltetrabenzoporphine

There total 3 articles about zinc(II) complex with monophenyltetrabenzoporphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

phenylacetic acid (103-82-2) + zinc(II) acetate dihydrate (5970-45-6) + 3,3-[1-(1-oxo-1H-isoindol-3-yl)methylene]-2,3-dihydro-1H-isoindol-1-one → zinc(II) complex with monophenyltetrabenzoporphine (120389-73-3) + zinc(II) complex with triphenyltetrabenzoporphine (120389-74-4) + zinc(II) tetraphenyltetrabenzoporphinate (80529-82-4)

Guidance literature:

In neat (no solvent); byproducts: (meso-diphenyltetrabenzoporphinato)zinc(II); mixt. of starting materials heated to 350°C; kept for 25 min at this temp.; cooled; extracted (benzene); extract evapd. to dryness; dissolved (benzene); complexes sepd. by chromy. (Al2O3, as eluent benzene-hexane, benzene-hexane-acetone, benzene-hexane-ethyl acetate); elem. anal.;

DOI:10.1023/A:1020715202738

Reference yield: 0.4%

zinc diacetate (557-34-6) + 3-benzylidenephthalimidine (5194-47-8) → zinc(II) complex with monophenyltetrabenzoporphine (120389-73-3) + zinc(II) complex with trans-diphenyltetrabenzoporphine (132040-17-6) + meso-diphenyltetrabenzoporphyrin zinc (132040-16-5) + zinc(II) complex with triphenyltetrabenzoporphine (120389-74-4) + zinc(II) tetraphenyltetrabenzoporphinate (80529-82-4)

Guidance literature:

A mixt. of benzylidenephthalimidine (BPI) and zinc acetate is heated at 360°C for 1 h under N2.; Product is washed with hot water and extd. with THF, evapn. gaves a residue, which is chromd. first (Al2O3-column, dioxane), purification by TLC on Al2O3, using a sovent mixture of benzene/hexane/THF (10:10:1) gives five major fractions.;

DOI:10.1016/S0020-1693(00)85087-2

Reference yield:

monophenyltetrabenzoporphine + zinc diacetate (557-34-6) → zinc(II) complex with monophenyltetrabenzoporphine (120389-73-3)

Guidance literature:

In pyridine; byproducts: CH3COOH; the Zn-contg. compd. was taken in a 100-fold molar excess compared to porphyrin; 298 K; Kinetics;

DOI:10.1023/B:RUGC.0000007663.33757.32

upstream raw materials:

phenylacetic acid

zinc(II) acetate dihydrate

zinc diacetate

3-benzylidenephthalimidine