{ReO(P(C₆H₅)2C₆H₄NH)2OCH₃}

Base Information

• Chemical Name: {ReO(P(C₆H₅)2C₆H₄NH)2OCH₃}
• CAS No.: 147392-57-2
• Molecular Formula: C₃₇H₃₃N₂O₂P₂Re
• Molecular Weight: 785.836
• Mol file: 147392-57-2.mol

Synonyms:

Chemical Property of {ReO(P(C₆H₅)2C₆H₄NH)2OCH₃}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {ReO(P(C₆H₅)2C₆H₄NH)2OCH₃}

There total 1 articles about {ReO(P(C₆H₅)2C₆H₄NH)2OCH₃} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

methanol (67-56-1) + tetra-n-butylammonium tetrachlorooxorhenate(V) + (2-diphenylphosphino)benzeneamine (65423-44-1) → {ReO(P(C6H5)2C6H4NH)2OCH3} (147392-57-2)

Guidance literature:

With sodium acetate; ethylene glycol; In methanol; addition of 0.5 ml of ethylene glycol and NaO2CMe (1.5 ml, 0.75 mol/ml in MeOH) drop by drop to a solution of 0.17 mmol of (NBu4)(ReOCl4) in a minimum amount of MeOH, addition of 0.34 mmol of the phosphine and stirring at 25°C for 2 hours;; washing with MeOH and drying under vacuum; elem. anal., UV-, IR-, NMR spectroscopy;;

DOI:10.1039/DT9930000605

Reference yield: 97.0%

{ReO(P(C6H5)2C6H4NH)2OCH3} (147392-57-2) + hydrogen bromide (10035-10-6,12258-64-9) → {ReO(P(C6H5)2C6H4NH)2Br} (147392-66-3)

Guidance literature:

In ethanol; addition of 0.45 mmol of 48 % HBr to a suspension of 0.04 mmol of the methoxy compound in 3 ml EtOH under stirring;; precipitation within 2 minutes; washing with EtOH and Et2O and drying under vacuum; elem. anal., UV-, IR-, NMR spectroscopy;;

DOI:10.1039/DT9930000605

Reference yield: 97.0%

{ReO(P(C6H5)2C6H4NH)2OCH3} (147392-57-2) + hydrogen iodide (10034-85-2) → {ReO(P(C6H5)2C6H4NH)2I} (147392-67-4)

Guidance literature:

In ethanol; addition of 0.45 mmol of 57 % HI to a suspension of 0.04 mmol of the methoxy compound in 3 ml EtOH under stirring;; precipitation within 2 minutes; washing with EtOH and Et2O and drying under vacuum; elem. anal., UV-, IR-, NMR spectroscopy;;

DOI:10.1039/DT9930000605

upstream raw materials:

methanol

(2-diphenylphosphino)benzeneamine

Downstream raw materials:

{ReO(P(C₆H₅)2C₆H₄NH)2OC₃H₇}

{ReO(P(C₆H₅)2C₆H₄NH)2OC₄H₉}

{ReO(P(C₆H₅)2C₆H₄NH)2OC₆H₅}

{ReO(P(C₆H₅)2C₆H₄NH)2Br}