glyoxal-bis(2,4,6-trimethylphenylimine)(cycloocta-1,5-diene)iridium tetrafluoroborate

Base Information

Chemical Name:glyoxal-bis(2,4,6-trimethylphenylimine)(cycloocta-1,5-diene)iridium tetrafluoroborate
CAS No.:1239599-61-1
Molecular Formula:BF₄*C₂₈H₃₆IrN₂
Molecular Weight:679.632
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of glyoxal-bis(2,4,6-trimethylphenylimine)(cycloocta-1,5-diene)iridium tetrafluoroborate

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Technology Process of glyoxal-bis(2,4,6-trimethylphenylimine)(cycloocta-1,5-diene)iridium tetrafluoroborate

There total 1 articles about glyoxal-bis(2,4,6-trimethylphenylimine)(cycloocta-1,5-diene)iridium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 32679-03-1
1,5-cyclooctadienebis(acetonitrile)iridium(I) tetrfluoroborate

: 56222-36-7
N,N'-bis(2,4,6-trimethylphenyl)ethanediimine

: 1239599-61-1
glyoxal-bis(2,4,6-trimethylphenylimine)(cycloocta-1,5-diene)iridium tetrafluoroborate

Guidance literature:: In dichloromethane; (CHNC6H2(CH3)3)2 soln. (1 equiv.) added to soln. of Ir complex at room temp. at stirring, stirred for 6 h; soln. added to Et2O, ppt. recrystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1016/j.poly.2011.11.058

Reference yield: 99.0%

: 201230-82-2
carbon monoxide

: 1239599-61-1
glyoxal-bis(2,4,6-trimethylphenylimine)(cycloocta-1,5-diene)iridium tetrafluoroborate

: 1357000-21-5
[iridium(I)(dicarbonyl)(1,4-bis(2,4,6-trimethylphenyl)-1,4-diaza-1,3-butadiene)](tetrafluoroborate)

Guidance literature:: In dichloromethane; CO bubbled into soln. of Ir complex at room temp. for 30 min at stirring; soln. poured into Et2O, ppt. collected, recrystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1016/j.poly.2011.11.058

Reference yield: 99.0%

: 13709-36-9
xenon difluoride

: 1239599-61-1
glyoxal-bis(2,4,6-trimethylphenylimine)(cycloocta-1,5-diene)iridium tetrafluoroborate

: 1239599-46-2
glyoxal-bis-(2,4,6-trimethylphenylimine)(cycloocta-1,5-diene)iridiumdifluoride tetrafluoroborate

Guidance literature:: In dichloromethane; byproducts: xenon; (Schlenk, N2) Ir-complex and XeF2 were placed into separate passivated vials in dry box, evacuated, CH2Cl2 was transferred by distillation at -196°C, warmed, XeF2 soln. was added at -196°C to complex, warmed to -90°C, agatated; the soln. was removed in vac.; elem. anal.;
DOI:10.1039/c0dt00066c