mer-{RuCl₃(C₆H₅CN)3}

Base Information

• Chemical Name: mer-{RuCl₃(C₆H₅CN)3}
• CAS No.: 132832-02-1
• Molecular Formula: C₂₁H₁₅Cl₃N₃Ru
• Molecular Weight: 516.799
• Mol file: 132832-02-1.mol

Synonyms:

Chemical Property of mer-{RuCl₃(C₆H₅CN)3}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mer-{RuCl₃(C₆H₅CN)3}

There total 2 articles about mer-{RuCl₃(C₆H₅CN)3} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

ruthenium trichloride hydrate (14898-67-0) + benzonitrile (100-47-0) → mer-{RuCl3(C6H5CN)3} (132832-02-1,71903-99-6)

Guidance literature:

In methanol; benzonitrile; the educt was heated in a mixt. of MeOH and benzonitrile at 80 °C for 45 min.; diethyl ether added to ppt. product;; pptn. from the react. mixt. and repptn. from PhCN/CH2Cl2 by addn. of diethyl ether; elem.anal.;;

DOI:10.1039/DT9910002401

Reference yield:

mer-{N(C4H9)4}{RuCl3(C6H5CN)3} → mer-{RuCl3(C6H5CN)3} (132832-02-1,71903-99-6)

Guidance literature:

In dichloromethane; benzonitrile; Electrochem. Process; electrochem. oxidn. at 0.5 V and -50°C in 10% PhCN/90% CH2Cl2 or at -55 °C in 70% PhCN/30% CH2Cl2;; elem.anal.;;

DOI:10.1039/DT9910002401

Reference yield: 87.0%

Cyclohexyl isocyanide (931-53-3) + mer-{RuCl3(C6H5CN)3} (132832-02-1,71903-99-6) + dichloromethane (75-09-2) → trans,trans,trans-[ruthenium(II)Cl2(NCPh)2(cyclohexylisocyanide)2]*dichloromethane (286960-60-9)

Guidance literature:

In ethanol; dichloromethane; (N2); heated under reflux, 4 h; filtered off under gravity; filtrate vol. reduced; pptd. (diethyl ether); sepd. off; recrystd. twice (CH2Cl2/diethyl ether); elem. anal.;

DOI:10.1016/S0020-1693(99)00581-2

upstream raw materials:

ruthenium trichloride hydrate

benzonitrile

Downstream raw materials:

trans,trans,trans-[ruthenium(II)Cl₂(NCPh)2(cyclohexylisocyanide)2]*dichloromethane

trans,trans,trans-[ruthenium(II)Cl₂(NCPh)2(tert-butylisocyanide)2]