(But-3-enyloxy)(tert-butyl)dimethylsilane

Base Information

• Chemical Name: (But-3-enyloxy)(tert-butyl)dimethylsilane
• CAS No.: 108794-10-1
• Molecular Formula: C10H22OSi
• Molecular Weight: 186.37
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID70434015
• Nikkaji Number: J1.181.404B
• Wikidata: Q82248310
• Mol file: 108794-10-1.mol

Synonyms:108794-10-1;BUT-3-ENYLOXY-TERT-BUTYL-DIMETHYL-SILANE;(but-3-enyloxy)(tert-butyl)dimethylsilane;(But-3-en-1-yloxy)-tert-butyldimethylsilane;but-3-enoxy-tert-butyl-dimethylsilane;(BUT-3-EN-1-YLOXY)(TERT-BUTYL)DIMETHYLSILANE;C10H22OSi;SCHEMBL4059577;DTXSID70434015;3-Buten-1-ol, TBDMS derivative;AKOS006330752;4-(tert-Butyldimethylsiloxy)-1-butene;1-(tert-butyldimethylsilyoxy)-3-butene;BS-25145;4-[(tert-Butyldimethylsilyl)oxy]-1-butene;3-Buten-1-ol, tert-butyldimethylsilyl ether;E87498

Chemical Property of (But-3-enyloxy)(tert-butyl)dimethylsilane

Chemical Property:

• PSA: 9.23000
• LogP: 3.58430
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 186.143991855
• Heavy Atom Count: 12
• Complexity: 144

Purity/Quality:

99% ^*data from raw suppliers

(But-3-en-1-yloxy)(tert-butyl)dimethylsilane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)[Si](C)(C)OCCC=C

Technology Process of (But-3-enyloxy)(tert-butyl)dimethylsilane

There total 5 articles about (But-3-enyloxy)(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

homoalylic alcohol (627-27-0) + tert-butyldimethylsilyl chloride (18162-48-6) → 4-[(tert-butyldimethylsilyl)oxy]-1-butene (108794-10-1)

Guidance literature:

With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 48h; Inert atmosphere;

DOI:10.1021/ol901691d

Reference yield: 96.0%

4-(tert-butyldimethylsilyloxy)-1-butyne (78592-82-2) → 4-[(tert-butyldimethylsilyl)oxy]-1-butene (108794-10-1)

Guidance literature:

With hydrogen; 3-azapentane-1,5-diamine; In methanol; at 25 ℃; for 6h;

DOI:10.1002/adsc.201100936

Reference yield: 88.0%

5-[tert-butyldimethylsilyloxy]pent-1-yne (61362-77-4) → 4-[(tert-butyldimethylsilyl)oxy]-1-butene (108794-10-1)

Guidance literature:

With [CuCl(IPr^Me)]; sodium t-butanolate; tert-butyl alcohol; In tetrahydrofuran; hexane; at 40 ℃; for 20h; chemoselective reaction; Inert atmosphere;

DOI:10.1002/adsc.201200200

upstream raw materials:

homoalylic alcohol

tert-butyldimethylsilyl chloride

N,N,2-trimethylpropionamide

4-(tert-butyldimethylsilyloxy)-1-butyne

Downstream raw materials:

N-[5-(tert-butyldimethylsilanyloxy)pent-2-enoyl]benzamide

(3R)-5-benzoylamino-3-[2-(tert-butyldimethylsilanyloxy)ethyl]-2-cyano-5-oxopentanoic acid methyl ester

(E)-3-methylene-6-phenylhex-5-en-1-ol

(-)-5-<(tert-butyl-dimethyl-silyl)-oxy>-1-phenyl-pentan-1-ol