bis(trimesitylgermylcarbodiimido)germylene

Base Information

Chemical Name:bis(trimesitylgermylcarbodiimido)germylene
CAS No.:261919-36-2
Molecular Formula:C₅₆H₆₆Ge₃N₄
Molecular Weight:1012.94
Hs Code.:

Synonyms:

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Chemical Property of bis(trimesitylgermylcarbodiimido)germylene

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Technology Process of bis(trimesitylgermylcarbodiimido)germylene

There total 1 articles about bis(trimesitylgermylcarbodiimido)germylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: germanium(II) chloride dioxane

: 62120-68-7
chlorotri(2,4,6-trimethylphenyl)germane

: 420-04-2
CYANAMID

: 261919-36-2
bis(trimesitylgermylcarbodiimido)germylene

Guidance literature:: With t-butyl lithium; In tetrahydrofuran; pentane; byproducts: LiCl; under N2 or Ar; t-BuLi in pentane added to H2NCN (molar ratio 2:1) in THF at -70°C; 30 min at room temp.; cooled to -60°C; 1 equiv. Mes3GeCl in THF added; 1 h at -60°C; 0.5 equiv. of GeCl2*dioxane in THF added; 16 h at -30°C; THF replaced by benzene; centrifuged; solvent evapd. under vac.;
DOI:10.1016/S0022-328X(99)00577-X

Reference yield: 75.0%

: 261919-36-2
bis(trimesitylgermylcarbodiimido)germylene

: 7732-18-5
water

: 261919-37-3
trimesitylgermylcarbodiimide

: 12024-99-6
Ge(OH)2

Guidance literature:: In benzene; hydrolysis of Ge compd. in benzene soln. at room temp. in open flask; crystals deposited on vessel walls near liq. surface; elem. anal.;
DOI:10.1016/S0022-328X(99)00577-X

Reference yield: 31.0%

: 1020-31-1,122983-47-5,881376-69-8
3,5-Di-tert-butylcatechol

: 261919-36-2
bis(trimesitylgermylcarbodiimido)germylene

: 261919-37-3
trimesitylgermylcarbodiimide

: 110577-20-3
2-germylene(6,8-di-t-butyl)-4,5-benzo-1,3-dioxolane

: 212907-09-0
trimesitylgermylcyanamide

Guidance literature:: In tetrahydrofuran; under N2 or Ar; soln. of 3,5-di-t-butylcatechol in THF added dropwise with stirring to Ge compd. (molar ratio 1:1) in THF; 4 h at room temp.; total yield of trimesitylgermylcyanamide and trimesitylgermylcarbodiimidewas 69%; solvent evapd. under vac.;
DOI:10.1016/S0022-328X(99)00577-X