2-(Diphenylphosphanylmethyl)prop-2-enyl-diphenylphosphane

Base Information

• Chemical Name: 2-(Diphenylphosphanylmethyl)prop-2-enyl-diphenylphosphane
• CAS No.: 120658-80-2
• Molecular Formula: C28H26P2
• Molecular Weight: 424.462
• DSSTox Substance ID: DTXSID20562236
• Nikkaji Number: J2.801.356F
• Wikidata: Q82446309
• Mol file: 120658-80-2.mol

Synonyms:120658-80-2;SCHEMBL8762951;DTXSID20562236;1,1-bis(diphenylphosphinomethyl)ethene;{2-[(Diphenylphosphanyl)methyl]prop-2-en-1-yl}(diphenyl)phosphane (non-preferred name)

Chemical Property of 2-(Diphenylphosphanylmethyl)prop-2-enyl-diphenylphosphane

Chemical Property:

• XLogP3: 6.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 8
• Exact Mass: 424.15097482
• Heavy Atom Count: 30
• Complexity: 411

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C(CP(C1=CC=CC=C1)C2=CC=CC=C2)CP(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of 2-(Diphenylphosphanylmethyl)prop-2-enyl-diphenylphosphane

There total 1 articles about 2-(Diphenylphosphanylmethyl)prop-2-enyl-diphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

2-chloromethyl-3-chloroprop-1-ene (1871-57-4) + lithium diphenylphosphide (65567-06-8,4541-02-0) → 1,1-bis<(diphenylphosphanyl)methyl>ethene (120658-80-2)

Guidance literature:

In tetrahydrofuran; 1.) -50 deg C to r.t., 2.) r.t., 12 h;

Reference yield: 96.0%

carbonylgold(I) chloride (50960-82-2) + 1,1-bis<(diphenylphosphanyl)methyl>ethene (120658-80-2) → μ-{1,1-bis((diphenylphosphino)methyl)ethene}digold(I) dichloride (120883-40-1)

Guidance literature:

In tetrahydrofuran; byproducts: CO; to a soln. of the bis(phosphine) is added at room temp. COAuCl; precipitate is separated, washed with toluene and pentane and recrystn. from acetone/hexane; elem. anal.;

Reference yield: 95.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,1-bis<(diphenylphosphanyl)methyl>ethene (120658-80-2) → {PtCl2((C6H5)2PCH2)2CCH2} (143021-64-1)

Guidance literature:

In dichloromethane; addn. of the ligand to a stirred suspn. of (Pt(cod)Cl2) in CH2Cl2, pptn. (within 5 min), addn. of Et2O; filtration, washing (Et2O), drying; elem. anal.;

DOI:10.1039/DT9920001929

upstream raw materials:

2-chloromethyl-3-chloroprop-1-ene

lithium diphenylphosphide

Downstream raw materials:

5-Methylene-1,1,3,3-tetraphenyl-1,3-diphosphoniacyclohexane Diiodide

cis-2-Methyl-1,3-bis(diphenylphosphino)propen

trans-2-Methyl-1,3-bis(diphenylphosphino)propen

1,1-Bis<(methyldiphenylphosphonio)methyl>ethen-diiodid