(η4-nornornadiene)Rh(2-(dicyclohexylphosphino)biphenyl)Cl

Base Information

Chemical Name:(η4-nornornadiene)Rh(2-(dicyclohexylphosphino)biphenyl)Cl
CAS No.:1287211-58-8
Molecular Formula:C₃₁H₃₉ClPRh
Molecular Weight:580.983
Hs Code.:

Synonyms:

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Chemical Property of (η4-nornornadiene)Rh(2-(dicyclohexylphosphino)biphenyl)Cl

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Technology Process of (η4-nornornadiene)Rh(2-(dicyclohexylphosphino)biphenyl)Cl

There total 1 articles about (η4-nornornadiene)Rh(2-(dicyclohexylphosphino)biphenyl)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: di-μ-chlorobis(norbornadiene)dirhodium(I)

: 247940-06-3
CyJohnPhos

: 1287211-58-8
(η4-nornornadiene)Rh(2-(dicyclohexylphosphino)biphenyl)Cl

Guidance literature:: In dichloromethane; dry CH2Cl2 added to mixt. of Rh complex and phosphine; stirred at 23°C for 1.5 h; solvent removed in vac.; pentane added; stirred overnight; filtered in air; ppt. washed with pentane; elem. anal.;
DOI:10.1021/om1009473

Reference yield: 98.0%

: 1287211-58-8
(η4-nornornadiene)Rh(2-(dicyclohexylphosphino)biphenyl)Cl

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 1287211-61-3
[(η4-nornornadiene)Rh(2-(dicyclohexylphosphino)biphenyl)][B(3,5-bis(trifluoromethyl)phenyl)4]

Guidance literature:: In dichloromethane; byproducts: NaCl; under N2; B compd. added to Rh complex; CH2Cl2 added; stirred for ca. 1 h; filtered through PTFE filter; solvent removed from filtrate in vac.; elem. anal.;
DOI:10.1021/om1009473

Reference yield:

: 1287211-58-8
(η4-nornornadiene)Rh(2-(dicyclohexylphosphino)biphenyl)Cl

: 1333-74-0
hydrogen

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 1287211-68-0
[RhH2(η6-2-(dicyclohexylphosphino)biphenyl)][B(3,5-bis(trifluoromethyl)phenyl)4]

Guidance literature:: In dichloromethane-d2; High Pressure; in NMR tube; Rh complex reacted with B compd. in undried CD2Cl2; degassed by freeze-pump-thaw cycles; pressurized with H2 (90 psi); reacted at room temp. for 4 d; headspace of tube degassed; recrystd. by vapor diffusion of CD2Cl2 soln.with pentane at -35°C; monitored by (1)H and (31)P NMR spectra;
DOI:10.1021/om1009473