Methyl N-(2,4-dichlorophenyl)carbamate

Base Information

Chemical Name:Methyl N-(2,4-dichlorophenyl)carbamate
CAS No.:2621-67-2
Molecular Formula:C₈H₇Cl₂NO₂
Molecular Weight:220.055
Hs Code.:
European Community (EC) Number:666-774-2
Nikkaji Number:J2.707.589D

Synonyms:Methyl N-(2,4-dichlorophenyl)carbamate;2621-67-2;SCHEMBL2095473;AKOS003267473

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl N-(2,4-dichlorophenyl)carbamate

Chemical Property:

XLogP3:2.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:218.9853839
Heavy Atom Count:13
Complexity:189

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)NC1=C(C=C(C=C1)Cl)Cl

Technology Process of Methyl N-(2,4-dichlorophenyl)carbamate

There total 4 articles about Methyl N-(2,4-dichlorophenyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

: 67-56-1
methanol

: 56843-28-8
2,4-dichlorobenzaldoxime

: 2621-67-2
methyl N-(2,4-dichlorophenyl)carbamate

Guidance literature:: With urea hydrogen peroxide; methyltrioxorhenium(VII); at 20 ℃;
DOI:10.1055/s-2004-829088

Reference yield:

: 2447-79-2
2,4-dichlorobenzamide

: 2621-67-2
methyl N-(2,4-dichlorophenyl)carbamate

Guidance literature:: Multi-step reaction with 2 steps

1: [N-(p-tolylsulfonyl)imino]phenyliodinane / dichloromethane / 4 h / 20 °C / Inert atmosphere

2: dichloromethane / 4.5 h / 20 °C / Inert atmosphere

With [N-(p-tolylsulfonyl)imino]phenyliodinane; In dichloromethane; 1: Hofmann rearrangement;
DOI:10.1021/jo300007c

Reference yield:

: 619-56-7
4-chlorobenzamide

: 2621-67-2
methyl N-(2,4-dichlorophenyl)carbamate

Guidance literature:: Multi-step reaction with 2 steps

1: N-Bromosuccinimide; potassium tert-butylate / 0.67 h / 80 °C

2: N-chloro-succinimide; toluene-4-sulfonic acid; palladium diacetate / 1,2-dichloro-ethane / 3.5 h / 60 °C / Sealed tube

With N-chloro-succinimide; N-Bromosuccinimide; potassium tert-butylate; palladium diacetate; toluene-4-sulfonic acid; In 1,2-dichloro-ethane;
DOI:10.1021/acs.joc.6b00329