(5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C₅H₁₁)

Base Information

Chemical Name:(5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C₅H₁₁)
CAS No.:183063-41-4
Molecular Formula:C₅₃H₄₇N₅O₂Ru
Molecular Weight:887.058
Hs Code.:

(5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C<sub>5</sub>H<sub>11</sub>)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C₅H₁₁)

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Technology Process of (5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C₅H₁₁)

There total 1 articles about (5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C₅H₁₁) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 75888-64-1
carbonyl(meso-tetrakis(4-tolyl)porphyrinato)ruthenium(II)

: 110-46-3
isopentyl nitrite

: 183063-41-4
(5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C₅H₁₁)

Guidance literature:: In dichloromethane; N2-atmosphere; excess nitrite, stirring and refluxing for 10 min (or prolonged stirring at room temp. for observation of intermediates without isolation); solvent removal (vac.), dissoln. in CH2Cl2, filtration over Al2O3, vol. reduction, addn. of hexanes, crystn. on slow evapn. in air; elem. anal.;
DOI:10.1021/ic970282c

Reference yield: 74.0%

: 75-09-2
dichloromethane

: 183063-41-4
(5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C₅H₁₁)

: 10294-33-4
boron tribromide

: (tetratolylporphyrinato dianion)Ru(NO)Br*0.9CH₂Cl₂

Guidance literature:: In dichloromethane; byproducts: BBr2(O-i-C5H11); under N2, Schlenk technique; soln. (0.08 ml) of BBr3 (0.08 mmol) added to soln. (20 ml) of Ru complex (0.056 mmol); kept (1 h); volume reduced to 5 ml; hexane (25 ml) added; supernatant discarded; solid washed with hexane (3x25 ml); dried (vac.); elem. anal.;
DOI:10.1016/j.ica.2004.06.031

Reference yield:

: 183063-41-4
(5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C₅H₁₁)

: 10294-34-5
boron trichloride

: 179930-28-0
chloride(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)

Guidance literature:: In dichloromethane; byproducts: BCl2(O-i-C5H11); under N2, Schlenk technique; soln. of BCl3 added to soln. of Ru complex;kept (1 h); volume reduced; hexane added; supernatant discarded; solid washed with hexane; dried (vac.);
DOI:10.1016/j.ica.2004.06.031