[MoCl2(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)]

Base Information

Chemical Name:[MoCl2(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)]
CAS No.:943343-70-2
Molecular Formula:C₄₆H₄₂Cl₂MoP₄
Molecular Weight:885.581
Hs Code.:

Synonyms:

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Chemical Property of [MoCl2(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)]

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Technology Process of [MoCl2(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)]

There total 1 articles about [MoCl2(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: Mo(dppe)(o-C₆H₄(PPhCH₂CH₂PPh₂)2)

: 100-44-7
benzyl chloride

: 943343-70-2
[MoCl₂(kappa.4-meso-o-C₆H₄(PPhC₂H₄PPh₂)2)]

Guidance literature:: In benzene; byproducts: Ph2PC2H4PPh2; PhCH2Cl (2 equiv.) was added to suspn. of Mo complex in C6H6; mixt. was stirred in dark at room temp. for 48 h; filtered; washed (C6H6, Et2O); dried (vac.);
DOI:10.1021/ic700371b

Reference yield: 92.0%

: 943343-70-2
[MoCl2(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)]

: 57-14-7
N,N-Dimethylhydrazine

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: trans-[MoCl(N)(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)]*0.5C6H6

Guidance literature:: In tetrahydrofuran; (N2, Schlenk) to a suspn. of complex in THF was added 1,1-dimethylhydrazine, the mixt. was stirred at room temp. for 90 min; volatiles were removed under reduced pressure, extd. with benzene, concd., hexane was added; elem. anal.;
DOI:10.1021/om7005485

Reference yield: 63.0%

: 17084-13-8
potassium hexafluorophosphate

: 75-09-2
dichloromethane

: 943343-70-2
[MoCl2(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)]

: 306-37-6
N,N'-Dimethylhydrazine dihydrochloride

: 955405-31-9
trans-[MoCl(NMe)(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)][PF6]*CH2Cl2

Guidance literature:: With triethyl amine; In tetrahydrofuran; (N2, Schlenk) to a mixt. of complex and hydrazine were added THF and (C2H5)3N, the mixt. was stirred at 60°C for 90 min, volatiles were removed, KPF6 and CH2Cl2 were added, stirred for 48 h at room temp.; filtered, diethyl ether was added; elem. anal.;
DOI:10.1021/om7005485