bis(indenyl)zirconium(IV) methyl chloride

Base Information

Chemical Name:bis(indenyl)zirconium(IV) methyl chloride
CAS No.:173772-80-0
Molecular Formula:C₁₉H₁₇ClZr
Molecular Weight:372.021
Hs Code.:

Synonyms:

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Chemical Property of bis(indenyl)zirconium(IV) methyl chloride

Chemical Property:

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Technology Process of bis(indenyl)zirconium(IV) methyl chloride

There total 6 articles about bis(indenyl)zirconium(IV) methyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 10026-11-6
zirconium(IV) chloride

: 95-13-6
1-indene

: 12148-49-1
bis(indenyl)zirconium(IV) dichloride

: 173772-80-0
bis(indenyl)zirconium(IV) methyl chloride

Guidance literature:: With methyllithium; In diethyl ether; pentane; (N2); a soln. of MeLi in Et2O added dropwise to indene in Et2O, stirred for 40 min at room temp., added at once to ZrCl4 slurred in pentane, stirred for 2 h; filtered, the filtrate discarded, the residue dried, extd. at reflux with CH2Cl2 for 5 h, dried to give Ind2ZrCl2 contg. 4 mol.% Ind2ZrClMe;
DOI:10.1016/S0022-328X(03)00124-4

Reference yield:

: bis(indenyl)zirconium dimethyl

: 76-83-5
trityl chloride

: 12148-49-1
bis(indenyl)zirconium(IV) dichloride

: 173772-80-0
bis(indenyl)zirconium(IV) methyl chloride

Guidance literature:: In ⁽²⁾H₈-toluene; byproducts: Ph3CCH3; N2 glovebox; Zr complex was treated with Ph3CCl (1-1.1 equiv.) in toluene-d8 at 90°C for 18 h; NMR monitoring; not isolated;
DOI:10.1021/om0305014

Reference yield:

: bis(indenyl)zirconium dimethyl

: 7758-95-4
lead(II) chloride

: 12148-49-1
bis(indenyl)zirconium(IV) dichloride

: 173772-80-0
bis(indenyl)zirconium(IV) methyl chloride

Guidance literature:: In toluene; (N2); a slurry of PbCl2 in toluene added to a soln. of Zr complex in toluene, stirred for 38 h at room temp. and 10 h at 40-45°C, filtered, evapd., treated with toluene and PbCl2, stirred for 30 min at room temp. and for 12 h at 40°C; not isolated, detected by NMR;
DOI:10.1016/S0022-328X(03)00124-4