[Ni(1,3-bis[di(o-methoxyphenyl)phosphanyl]propane)Cl₂]

Base Information

• Chemical Name: [Ni(1,3-bis[di(o-methoxyphenyl)phosphanyl]propane)Cl₂]
• CAS No.: 353514-15-5
• Molecular Formula: C₃₁H₃₄Cl₂NiO₄P₂
• Molecular Weight: 662.152
• Mol file: 353514-15-5.mol

Synonyms:

Chemical Property of [Ni(1,3-bis[di(o-methoxyphenyl)phosphanyl]propane)Cl₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [Ni(1,3-bis[di(o-methoxyphenyl)phosphanyl]propane)Cl₂]

There total 3 articles about [Ni(1,3-bis[di(o-methoxyphenyl)phosphanyl]propane)Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

nickel(II) chloride hexahydrate + 1,3-bis[di(2-methoxyphenyl)-phosphino]propane (116163-96-3) → [Ni(1,3-bis[di(o-methoxyphenyl)phosphanyl]propane)Cl2] (353514-15-5)

Guidance literature:

In ethanol; chloroform; all manipulations under dry Ar or dry N2; Ni compd. dissolved in EtOH and mixed with equimolar amt. of soln. of ligand in CHCl3; ppt. was filtered off and dried in vac.; elem. anal.;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + nickel(II) acetate tetrahydrate (6018-89-9) + 1,3-bis[di(2-methoxyphenyl)-phosphino]propane (116163-96-3) → [Ni(1,3-bis[di(o-methoxyphenyl)phosphanyl]propane)Cl2] (353514-15-5)

Guidance literature:

In diethyl ether; ethanol; all manipulations under dry Ar or dry N2; equimolar amts. of Ni compd. and ligand were mixed in EtOH, mixt. heated under reflux for 3.5 h, cooling, addn. of soln. of HCl in Et2O; ppt. was filtered off and dried in vac.; elem. anal.;

Reference yield:

dichloromethane (75-09-2) + nickel(II) acetate tetrahydrate (6018-89-9) + 1,3-bis[di(2-methoxyphenyl)-phosphino]propane (116163-96-3) → [Ni(1,3-bis[di(o-methoxyphenyl)phosphanyl]propane)Cl2] (353514-15-5) + [Ni(1,3-bis[di(o-methoxyphenyl)phosphanyl]propane)2](acetate)2

Guidance literature:

In methanol; dichloromethane; all manipulations under dry Ar or dry N2; Ni compd. dried in vac., then dissolved in CH2Cl2, mixed with soln. of ligand in CH2Cl2, stirred overnight; crystn. after 4 months at 4°C;

upstream raw materials:

1,3-bis[di(2-methoxyphenyl)-phosphino]propane

dichloromethane

nickel(II) acetate tetrahydrate

hydrogenchloride