trans-(benzonitrile)-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum

Base Information

• Chemical Name: trans-(benzonitrile)-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum
• CAS No.: 1247793-74-3
• Molecular Formula: C₂₃H₂₁Cl₂N₃O₂Pt
• Molecular Weight: 637.425
• Mol file: 1247793-74-3.mol

Synonyms:

Chemical Property of trans-(benzonitrile)-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-(benzonitrile)-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum

There total 1 articles about trans-(benzonitrile)-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

trans-bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + N-(2-methoxybenzylidene)methanamine N-oxide (33499-30-8) → trans-(benzonitrile)-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum (1247793-74-3)

Guidance literature:

In chloroform; soln. Pt complex and nitrone in CHCl3 was stirred at room temp. for 48 h; solvent was evapd., product was purified by chromy. on silica (CH2Cl2); elem. anal.;

DOI:10.1039/c0dt00360c

Reference yield: 83.0%

hexamethylenetetramine (100-97-0) + trans-(benzonitrile)-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum (1247793-74-3) → trans-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN4][hexamethylenetetramine-κN1]platinum + [μ-hexamethylenetetramine-κN1:κN3]tetrachlorobis[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN4]diplatinum

Guidance literature:

In chloroform; at 20 ℃; for 96h;

DOI:10.1039/c7dt02406a

Reference yield: 73.0%

trans-(benzonitrile)-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum (1247793-74-3) + 7-nitro-1,3,5-triazaadamantane (14612-28-3) → trans-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)][7-nitro-1,3,5-triazaadamantane-κN(1)]platinum (1247793-93-6) + [μ-7-nitro-1,3,5-triazaadamantane-κN1:κN3]tetrachlorobis[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN4]diplatinum (1247794-14-4)

Guidance literature:

In chloroform; soln. Pt complex and 7-nitro-1,3,5-triaza-adamantane in CHCl3 was stirred at room temp. for 2 weeks; solvent was evapd., product was purified by chromy. on silica (CH2Cl2-Et2O 98:2); elem. anal.;

DOI:10.1039/c0dt00360c

upstream raw materials:

trans-bis(benzonitrile)dichloroplatinum(II)

N-(2-methoxybenzylidene)methanamine N-oxide

Downstream raw materials:

trans-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)][7-nitro-1,3,5-triazaadamantane-κN(1)]platinum

[μ-7-nitro-1,3,5-triazaadamantane-κN¹:κN³]tetrachlorobis[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN⁴]diplatinum

trans-dichloro[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)][pyridine-κN(1)]platinum