Tribromo(iodo)silane

Base Information

• Chemical Name: Tribromo(iodo)silane
• CAS No.: 13536-76-0
• Molecular Formula: Br3ISi
• Molecular Weight: 394.702
• DSSTox Substance ID: DTXSID00596312
• Wikidata: Q16736816
• Mol file: 13536-76-0.mol

Synonyms:Tribromo(iodo)silane;iodotribromosilane;13536-76-0;DTXSID00596312;Q16736816

Chemical Property of Tribromo(iodo)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 393.63436
• Heavy Atom Count: 5
• Complexity: 28.4

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Si](Br)(Br)(Br)I

Technology Process of Tribromo(iodo)silane

There total 3 articles about Tribromo(iodo)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromine (7726-95-6) + silicon tetraiodide (13465-84-4) → tribromo iodosilane (13536-76-0) + tetrabromosilane (7789-66-4)

Guidance literature:

In carbon disulfide;

Reference yield:

iodine(I) bromide (7789-33-5) + silicon (7440-21-3) → tribromo iodosilane (13536-76-0) + diiododibromosilane (13550-39-5) + triiodobromosilane (13536-68-0) + tetrabromosilane (7789-66-4) + silicon tetraiodide (13465-84-4)

Guidance literature:

In neat (no solvent); distillation of BrI or passing BrI in a H2 stream to crystalline Si near red heat;;

Reference yield:

iodine (7553-56-2,12190-71-5,8031-47-8) + tetrabromosilane (7789-66-4) + silicon (7440-21-3) → tribromo iodosilane (13536-76-0) + diiododibromosilane (13550-39-5) + triiodobromosilane (13536-68-0) + silicon tetraiodide (13465-84-4)

Guidance literature:

In neat (no solvent); byproducts: SiBr4; distillation of a solution of I2 and SiBr4 or passing the mixture in a H2 stream to crystalline Si near red heat;;

upstream raw materials:

iodine

tetrabromosilane

silicon

bromine