1-(diphenylphosphino)-1'-(methylsulfanyl)ferrocene

Base Information

• Chemical Name: 1-(diphenylphosphino)-1'-(methylsulfanyl)ferrocene
• CAS No.: 244009-88-9
• Molecular Formula: C₂₃H₂₁FePS
• Molecular Weight: 416.307

Synonyms:

Chemical Property of 1-(diphenylphosphino)-1'-(methylsulfanyl)ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 1-(diphenylphosphino)-1'-(methylsulfanyl)ferrocene

There total 1 articles about 1-(diphenylphosphino)-1'-(methylsulfanyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

1,1'-dilithioferrocene (33272-09-2) + Dimethyldisulphide (624-92-0) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → 1-(diphenylphosphino)-1'-(methylsulfanyl)ferrocene (244009-88-9)

Guidance literature:

In hexane; byproducts: 1,1'-bis(methylthio)ferrocene, 1,1'-bis(diphenylphosphino)ferrocene; under N2; Fe-contg. compd. was suspended in dry hexane; to the dropping funnel was added dimethyl disulfide (0.8 equiv.), chlorodiphenylphosphine (0.8 equiv.) and dry hexane; this soln. was added dropwise to the suspn. of Fe-contg. compd.; room temp.; stirring for 15 h; water was added and the suspn. was stirred for further 1 h; the solid was filtered off; sepn. of the layers; column chromy. (alumina, diethyl ether-hexane, 1:4); elem. anal.;

DOI:10.1039/b205653d

Reference yield: 91.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1-(diphenylphosphino)-1'-(methylsulfanyl)ferrocene (244009-88-9) → dichloro[1-(diphenylphosphino)-1'-(methylthio)ferrocene]platinum(II) (494830-28-3)

Guidance literature:

In dichloromethane; toluene; under N2; Fe-contg. compd. (0.6 mmol) was dissolved in toluene and addedto Pt-contg. compd. (0.53 mmol) dissolved in CH2Cl2; stirring for 15 h at room temp.; the ppt. was filtered off and washed with dry hexane and dry CH2Cl2; recrystn. by dissolution in CH2Cl2 and layering with hexane; elem. anal.;

DOI:10.1039/b205653d

Reference yield: 81.0%

dichloro(cycloocta-1,5-diene)palladium (II) (12107-56-1) + 1-(diphenylphosphino)-1'-(methylsulfanyl)ferrocene (244009-88-9) → dichloro[1-(diphenylphosphino)-1'-(methylthio)ferrocene]palladium(II) (494830-29-4)

Guidance literature:

In chloroform; toluene; under N2; Fe-contg. compd. (0.6 mmol) was dissolved in toluene and addedto Pd-contg. compd. (0.53 mmol) dissolved in chloroform; stirring for 1 5 h at room temp.; the soln. was concd. to ppt. a red solid; it was filtered off and washedwith dry hexane; recrystn. by dissolution in CH2Cl2 and layering with h exane; elem. anal.;

DOI:10.1039/b205653d

upstream raw materials:

1,1'-dilithioferrocene

Dimethyldisulphide

chloro-diphenylphosphine

Downstream raw materials:

Ag(Fe(C₅H₄SCH₃)(C₅H₄P(C₆H₅)2))2⁽¹⁺⁾*BF₄^(1-) = [Ag(Fe(C₅H₄SCH₃)(C₅H₄P(C₆H₅)2))2]BF₄

[1-(diphenylphosphino)-1'-(methylthio)ferrocene]tetracarbonylmolybdenum⁽⁰⁾

[1-(diphenylphosphino)-1'-(methylthio)ferrocene]pentacarbonylmolybdenum⁽⁰⁾

dibromo[1-(diphenylphosphino)-1'-(methylthio)ferrocene]nickel(II)

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