[(Chlorodimethylsilyl)methyl]trimethyl silane

Base Information

• Chemical Name: [(Chlorodimethylsilyl)methyl]trimethyl silane
• CAS No.: 13683-11-9
• Molecular Formula: C6H17ClSi2
• Molecular Weight: 180.825
• European Community (EC) Number: 603-978-2
• DSSTox Substance ID: DTXSID401256298
• Nikkaji Number: J1.046.329G
• Mol file: 13683-11-9.mol

Synonyms:[(Chlorodimethylsilyl)methyl]trimethylsilane;[(Chlorodimethylsilyl)methyl]trimethyl silane;13683-11-9;SCHEMBL996306;MISGXMIUJANMGE-UHFFFAOYSA-N;DTXSID401256298;1-chloro-1,1,3,3,3-pentamethyl-(disilylmethane)

Chemical Property of [(Chlorodimethylsilyl)methyl]trimethyl silane

Chemical Property:

• Vapor Pressure: 4.32mmHg at 25°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 180.0557313
• Heavy Atom Count: 9
• Complexity: 93.7

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C)C[Si](C)(C)Cl

Technology Process of [(Chlorodimethylsilyl)methyl]trimethyl silane

There total 3 articles about [(Chlorodimethylsilyl)methyl]trimethyl silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

dimethyl(2,4,6-trimethoxyphenyl)[(trimethylsilyl)methyl]silane (1440146-65-5) → 1,2,3-trimethoxybenzene (621-23-8) + trimethylsilyl(dimethylchlorosilyl)methane (13683-11-9)

Guidance literature:

With hydrogenchloride; In diethyl ether; at 0 ℃; for 2h; chemoselective reaction; Inert atmosphere;

DOI:10.1021/om400190q

Reference yield:

Chloro(chloromethyl)dimethylsilane (1719-57-9) → 1,1,3,3,5,5-hexamethyl-[1,3,5]trisilinane (1627-99-2) + 1,1,3,3-tetramethyl-1,3-disiletane (1627-98-1) + chloro-trimethyl-silane (75-77-4) + trimethylsilyl(dimethylchlorosilyl)methane (13683-11-9)

Guidance literature:

With K/Na; at 280 - 300 ℃; under 0.1 - 1 Torr; Yield given. Further byproducts given. Yields of byproduct given;

Reference yield:

bis(trimethylsilyl)methane (2117-28-4) → trimethylsilyl(dimethylchlorosilyl)methane (13683-11-9) + bis(chlorodimethylsilyl)methane (5357-38-0,124211-70-7)

Guidance literature:

With boron trichloride; at 160 ℃; for 120h; ampoule;

upstream raw materials:

Chloro(chloromethyl)dimethylsilane

bis(trimethylsilyl)methane

dimethyl(2,4,6-trimethoxyphenyl)[(trimethylsilyl)methyl]silane

Downstream raw materials:

{2-[4-(Dimethyl-trimethylsilanylmethyl-silanyl)-phenoxy]-ethyl}-diethyl-amine

[3-(Dimethyl-trimethylsilanylmethyl-silanyl)-prop-2-ynyl]-benzene

methylsilane

dimethylsilane