[Ni₂(PhP(C₆H₄S-2)2)2]

Base Information

Chemical Name:[Ni₂(PhP(C₆H₄S-2)2)2]
CAS No.:436154-27-7
Molecular Formula:C₃₆H₂₆Ni₂P₂S₄
Molecular Weight:766.194
Hs Code.:

[Ni<sub>2</sub>(PhP(C<sub>6</sub>H<sub>4</sub>S-2)2)2]

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Chemical Property of [Ni₂(PhP(C₆H₄S-2)2)2]

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Technology Process of [Ni₂(PhP(C₆H₄S-2)2)2]

There total 3 articles about [Ni₂(PhP(C₆H₄S-2)2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 22775-90-2
dichloro(2,2'-bipyridine)nickel(II)

: 141-52-6
sodium ethanolate

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: 436154-27-7
[NiPC₆H₅(C₆H₄S)2]2

Guidance literature:: In ethanol; soln. of NaOEt added over a period of 10 min to a suspension of PPh(C6H4SH)2 in ethanol under Ar, then NiCl2(C5H4N)2 added and stirred overnightat room temp.; precipitated solid filtered, washed (ethanol), dried in vacuo; elem. anal.;
DOI:10.1002/1099-0682(200203)2002:4<826::aid-ejic826>3.0.co;2-m

Reference yield: 70.0%

: nickel(II) chloride hexahydrate

: 141-52-6
sodium ethanolate

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: 436154-27-7
[NiPC₆H₅(C₆H₄S)2]2

Guidance literature:: In ethanol; soln. of NaOEt added over a period of 10 min to a suspension of PPh(C6H4SH)2 in ethanol under Ar, then NiCl2*6H2O added at room temp.; precipitated solid filtered, washed (ethanol), dried in vacuo; elem. anal.;
DOI:10.1002/1099-0682(200203)2002:4<826::aid-ejic826>3.0.co;2-m

Reference yield:

: 7440-02-0
nickel

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: 436154-27-7
[Ni₂(PhP(C₆H₄S-2)2)2]

Guidance literature:: With (CH₃)4NClO₄; In acetonitrile; Electrolysis; under N2; soln. of org. ligand (0.380 mmol) electrolyzed in the presenceof Me4NClO4 using Ni anode (10 mA, 2 h); Ni (22.0 mg) dissolved from an ode (E(f) = 0.50 mol/F); solid washed with CH3CN and ether, dried under vac.; elem. anal.;
DOI:10.1002/ejic.200900941