cis,fac-[Ir(CO)₂I₃(COCH₃)]As(phenyl)₄

Base Information

• Chemical Name: cis,fac-[Ir(CO)₂I₃(COCH₃)]As(phenyl)₄
• CAS No.: 681445-92-1
• Molecular Formula: C₄H₃I₃IrO₃*C₂₄H₂₀As
• Molecular Weight: 1055.34
• Mol file: 681445-92-1.mol

Synonyms:

Chemical Property of cis,fac-[Ir(CO)₂I₃(COCH₃)]As(phenyl)₄

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of cis,fac-[Ir(CO)₂I₃(COCH₃)]As(phenyl)₄

There total 4 articles about cis,fac-[Ir(CO)₂I₃(COCH₃)]As(phenyl)₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

[Ir(acetyl)(μ-I)(CO)I2]2[AsPh4]2 + carbon monoxide (201230-82-2) → mer,trans-[Ir(acetyl)(CO)2I3][AsPh4] (681445-92-1,879559-49-6)

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); a soln. of Ir complex equilibrated with CO (1 atm) for 1 h, photolyzed for 2 h; concd. (vac.), layered with Et2O, crystals sepd., washed (Et2O), dried (N2); elem. anal.;

DOI:10.1021/ic0513033

Reference yield:

methanol (67-56-1) + cis,fac-[Ir(CO)2I3Me]AsPh4 (259794-29-1,36542-09-3) + carbon monoxide (201230-82-2) + methyl iodide (74-88-4) → mer,trans-[Ir(acetyl)(CO)2I3][AsPh4] (681445-92-1,879559-49-6) + cis,fac-[Ir(CO)2I3(COCH3)]As(phenyl)4 (681445-92-1,879559-49-6)

Guidance literature:

In tetrahydrofuran; Ir-complex was dissolved in THF, MeOH and MeI were added, CO was bubbled, warmed to 40°C for 3 d; evapd. to dryness in vacuo, recrystd. by dissolving in CH2Cl2, layered with Et2O, cooled to 5°C, dried in vacuo; elem. anal.;

DOI:10.1021/ja039464y

Reference yield:

methanol (67-56-1) + cis,fac-[Ir(CO)2I3Me]AsPh4 (259794-29-1,36542-09-3) + carbon monoxide (201230-82-2) + methyl iodide (74-88-4) → mer,trans-[Ir(acetyl)(CO)2I3][AsPh4] (681445-92-1,879559-49-6) + cis,fac-[Ir(CO)2I3(COCH3)]As(phenyl)4 (681445-92-1,879559-49-6)

Guidance literature:

In tetrahydrofuran; Ir-complex was dissolved in THF, MeOH and MeI were added, CO was bubbled, warmed to 40°C for 3 d; evapd. to dryness in vacuo, recrystd. by dissolving in CH2Cl2, layered with Et2O, cooled to 5°C, dried in vacuo; elem. anal.;

DOI:10.1021/ja039464y

upstream raw materials:

methanol

cis,fac-[Ir(CO)2I₃Me]AsPh₄

carbon monoxide

methyl iodide