Mo(CO)3(C₆H₅P(CH₂CH₂S)2CH₂CH₂)

Base Information

• Chemical Name: Mo(CO)3(C₆H₅P(CH₂CH₂S)2CH₂CH₂)
• CAS No.: 147210-31-9
• Molecular Formula: C₁₅H₁₇MoO₃PS₂
• Molecular Weight: 436.344
• Mol file: 147210-31-9.mol

Synonyms:

Chemical Property of Mo(CO)3(C₆H₅P(CH₂CH₂S)2CH₂CH₂)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mo(CO)3(C₆H₅P(CH₂CH₂S)2CH₂CH₂)

There total 3 articles about Mo(CO)3(C₆H₅P(CH₂CH₂S)2CH₂CH₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

2(CH3)4N(1+)*Mo(CO)3(C6H5P(CH2CH2S)2)(2-)=[(CH3)4N]2[Mo(CO)3(C6H5P(CH2CH2S)2)] + 1,2-dichloro-ethane (107-06-2,52399-93-6) → Mo(CO)3(C6H5P(CH2CH2S)2CH2CH2) (147210-31-9)

Guidance literature:

In acetonitrile; N2-atmosphere; dropwise addn. of 1 equiv. dichloroalkane to Mo-complex, standing for 30 min (pptn.); decantation, drying (vac.), washing (MeOH), drying (vac.); elem. anal.;

DOI:10.1021/ic961143i

Reference yield: 43.0%

3-phenyl-3-phosphapentane-1,5-dithiol (3190-78-1) + ethylene dibromide (106-93-4) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → Mo(C6H12(PC6H5)S2)(CO)3 (147210-31-9)

Guidance literature:

With MeCN; Me₄NOH; In acetonitrile; byproducts: Me4NBr; N2-atmosphere; refluxing hexacarbonyl for 4 h, addn. to PN2 ligand (treated with Me4NOH/MeOH following evapn.), stirring at room temp. for 8-10 h, dropwise addn. of C2H4Br2, stirring at room temp. for 2 h; solvent removal (vac.), washing (hexanes), dissoln. in CH2Cl2, filtration through Al2O3, concn., chromy. (Al2O3, CH2Cl2/hexanes=4:1 v/v), recrystn. (CH2Cl2/Et2O); elem. anal.;

DOI:10.1021/ic970670e

Reference yield:

2(CH3)4N(1+)*(C6H5)P(CH2CH2S)2(2-)=((CH3)4N)2P(C6H5)(CH2CH2S)2 + 1,2-dichloro-ethane (107-06-2,52399-93-6) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → Mo(C6H12(PC6H5)S2)(CO)3 (147210-31-9)

Guidance literature:

In acetonitrile; Mo-complex soln. refluxing (3 h), treatment with soln. of (Me4N)2PhP(CH2CH2S)2 (room temp., 20 h), ClCH2CH2Cl soln. add. (room temp., 30 min);

DOI:10.1039/c39930000054

upstream raw materials:

3-phenyl-3-phosphapentane-1,5-dithiol

ethylene dibromide

molybdenum hexacarbonyl

1,2-dichloro-ethane

Downstream raw materials:

MoH(C₆H₁₂(PC₆H₅)S₂)(CO)3⁽¹⁺⁾*CF₃SO₃^(1-)=[MoH(C₆H₁₂(PC₆H₅)S₂)(CO)3]CF₃SO₃

Mo(CO)2(C₆H₅P(CH₂CH₂S)2CH₂CH₂)Br₂