[(Pd(κ2C,N-N,N',N''-tris(2-anisyl)guanidine(-H)))2(μ-acetate)2]

Base Information

• Chemical Name: [(Pd(κ2C,N-N,N',N''-tris(2-anisyl)guanidine(-H)))2(μ-acetate)2]
• CAS No.: 1262511-60-3
• Molecular Formula: C₄₈H₅₀N₆O₁₀Pd₂
• Molecular Weight: 1083.8
• Mol file: 1262511-60-3.mol

Synonyms:

Chemical Property of [(Pd(κ2C,N-N,N',N''-tris(2-anisyl)guanidine(-H)))2(μ-acetate)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(Pd(κ2C,N-N,N',N''-tris(2-anisyl)guanidine(-H)))2(μ-acetate)2]

There total 1 articles about [(Pd(κ2C,N-N,N',N''-tris(2-anisyl)guanidine(-H)))2(μ-acetate)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N,N',N''-tris(2-anisyl)guanidine (95131-13-8) + palladium diacetate (3375-31-3) → [(Pd(κ2C,N-N,N',N''-tris(2-anisyl)guanidine(-H)))2(μ-acetate)2] (1262511-60-3) + trans-[(Pd(κN-N,N',N''-tris(2-anisyl)guanidine)(μ-acetate)(acetate))2] (1262836-38-3)

Guidance literature:

In dichloromethane; stirring mixt. of palladium compd. and guanidine deriv. in CH2Cl2 at 35°C for 2 ds in air; not separated, NMR;

DOI:10.1021/om1009445

Reference yield: 90.0%

dichloromethane (75-09-2) + [(Pd(κ2C,N-N,N',N''-tris(2-anisyl)guanidine(-H)))2(μ-acetate)2] (1262511-60-3) + lithium bromide (7550-35-8) → [(Pd(κ2C,N-N,N',N''-tris(2-anisyl)guainidine(-H)))2(μ-Br)2]*2dichloromethane

Guidance literature:

In ethanol; water; (N2, Schlenk technique); addn. of aq. soln. of LiBr to suspn. of palladium compd. in dry ethanol, stirring at 78°C for 8 h; evapn., extn. (CH2Cl2), washing with dist. water, drying over MgSO4, evapn., recrystn. (CH2Cl2) at room temp. for several hs, elem. anal.;

DOI:10.1021/om1009445

upstream raw materials:

N,N',N''-tris(2-anisyl)guanidine

palladium diacetate