[Rh(cycloocta-1,5-diene)(1,1'-bis(diphenylphosphino)ferrocene)](PF₆)

Base Information

Chemical Name:[Rh(cycloocta-1,5-diene)(1,1'-bis(diphenylphosphino)ferrocene)](PF₆)
CAS No.:862260-84-2
Molecular Formula:C₄₂H₄₀FeP₂Rh*F₆P
Molecular Weight:910.444
Hs Code.:

[Rh(cycloocta-1,5-diene)(1,1'-bis(diphenylphosphino)ferrocene)](PF<sub>6</sub>)

Synonyms:

Suppliers and Price of [Rh(cycloocta-1,5-diene)(1,1'-bis(diphenylphosphino)ferrocene)](PF₆)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [Rh(cycloocta-1,5-diene)(1,1'-bis(diphenylphosphino)ferrocene)](PF₆)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [Rh(cycloocta-1,5-diene)(1,1'-bis(diphenylphosphino)ferrocene)](PF₆)

There total 1 articles about [Rh(cycloocta-1,5-diene)(1,1'-bis(diphenylphosphino)ferrocene)](PF₆) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 12150-46-8
1,1'-bis-(diphenylphosphino)ferrocene

: ammonium hexafluorophosphate

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 862260-84-2
[Rh(cycloocta-1,5-diene)(1,1'-bis(diphenylphosphino)ferrocene)](PF₆)

Guidance literature:: In methanol; (N2); using Schlenk techniques; dissolving of (RhCl(COD))2 in MeOH; addn. of dppf, stirring of suspn. for 1 h at room temp., addn. of NH4PF6; pptn., filtration, washing 3 times with MeOH; drying under vac., elem. anal.;
DOI:10.1021/om050241l

Reference yield: 85.0%

: 862260-84-2
[Rh(cycloocta-1,5-diene)(1,1'-bis(diphenylphosphino)ferrocene)](PF₆)

: 201230-82-2
carbon monoxide

: 862260-73-9
[Rh(CO)2(1,1'-bis(diphenylphosphino)ferrocene)](PF₆)

Guidance literature:: In dichloromethane; (N2); using Schlenk techniques; dissolving of Rh(dppf)(COD)(PF6) in CH2Cl2; bubbling of CO through soln. for 5 min; concn. to dryness under vac., suspending in n-pentane; stirring at room temp. for 10 min; filtration, drying under a slight stream of N2; elem. anal.;
DOI:10.1021/om050241l

Reference yield:

: 862260-84-2
[Rh(cycloocta-1,5-diene)(1,1'-bis(diphenylphosphino)ferrocene)](PF₆)

: 201230-82-2
carbon monoxide

: 1333-74-0
hydrogen

: 311820-28-7,312304-84-0
[RhH(CO)2(1,1'-bis(diphenylphosphino)ferrocene)]

: 311820-28-7,312304-84-0
[RhH(CO)2(1,1'-bis(diphenylphosphino)ferrocene)]

Guidance literature:: In tetrahydrofuran; byproducts: COD; High Pressure; (N2); using Schlenk techniques; dissolving of Rh(COD)(dppf)(PF6) in THF;introducing into high pressure IR cell; pressurizing with syngas (CO/H2 , 1:2) to 45 bar; heating from 25 to 60°C with stirring; cooling; monitoring by IR;
DOI:10.1021/om050241l