PtMe₂(4,4'-di-tert-butyl-2,2'-bipyridine)Br(CH₂-4-C₆H₄CONH-t-Bu)

Base Information

• Chemical Name: PtMe₂(4,4'-di-tert-butyl-2,2'-bipyridine)Br(CH₂-4-C₆H₄CONH-t-Bu)
• CAS No.: 1161399-44-5
• Molecular Formula: C₃₂H₄₆BrN₃OPt
• Molecular Weight: 763.721
• Mol file: 1161399-44-5.mol

Synonyms:

Chemical Property of PtMe₂(4,4'-di-tert-butyl-2,2'-bipyridine)Br(CH₂-4-C₆H₄CONH-t-Bu)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PtMe₂(4,4'-di-tert-butyl-2,2'-bipyridine)Br(CH₂-4-C₆H₄CONH-t-Bu)

There total 1 articles about PtMe₂(4,4'-di-tert-butyl-2,2'-bipyridine)Br(CH₂-4-C₆H₄CONH-t-Bu) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(4,4'-di-tert-butyl-2,2'-bipyridine)dimethylplatinum(II) + 4-(bromomethyl)-N-(tert-butyl)benzamide (162330-18-9) → PtMe2(4,4'-di-tert-butyl-2,2'-bipyridine)Br(CH2-4-C6H4CONH-t-Bu) (1161399-44-5)

Guidance literature:

In acetone; (under N2, Schlenk); mixt. of Pt-complex and ligand in acetone stirred for 5 h at room temp.; solvent evapd. under vac., washed with H2O, then pentane, dried in vacuo; elem. anal.;

DOI:10.1039/b900855a

Reference yield: 92.0%

1,4-pyrazine (290-37-9) + silver tetrafluoroborate (14104-20-2) + PtMe2(4,4'-di-tert-butyl-2,2'-bipyridine)Br(CH2-4-C6H4CONH-t-Bu) (1161399-44-5) → [PtMe2(4,4'-di-tert-butyl-2,2'-bipyridine)(CH2-4-C6H4CONH-t-Bu)]2(μ-pyrazine)(BF4)2

Guidance literature:

In acetone; byproducts: AgBr; (under N2, Schlenk); soln. of AgBF4 in acetone added dropwise to Pt-complex in acetone, stirred for 1 h, filtered, soln. of pyrazine added, stirred for 12 h at room temp.; solvent evapd., recrystd. from CH2Cl2/pentane; elem. anal.;

DOI:10.1039/b900855a

Reference yield: 90.0%

1,4-pyrazine (290-37-9) + silver(I) hexafluorophosphate (26042-63-7) + PtMe2(4,4'-di-tert-butyl-2,2'-bipyridine)Br(CH2-4-C6H4CONH-t-Bu) (1161399-44-5) → [PtMe2(4,4'-di-tert-butyl-2,2'-bipyridine)(CH2-4-C6H4CONH-t-Bu)]2(μ-pyrazine)(PF6)2

Guidance literature:

In acetone; byproducts: AgBr; (under N2, Schlenk); soln. of AgPF6 in acetone added dropwise to Pt-complex in acetone, stirred for 1 h, filtered, soln. of pyrazine added, stirred for 12 h at room temp.; solvent evapd., recrystd. from CH2Cl2/pentane; elem. anal.;

DOI:10.1039/b900855a

upstream raw materials:

4-(bromomethyl)-N-(tert-butyl)benzamide