[Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(acetonitrile)(benzoate-κ1O)]

Base Information

• Chemical Name: [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(acetonitrile)(benzoate-κ1O)]
• CAS No.: 1068652-98-1
• Molecular Formula: C₃₉H₃₈N₅O₄PRu
• Molecular Weight: 772.806
• Mol file: 1068652-98-1.mol

Synonyms:

Chemical Property of [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(acetonitrile)(benzoate-κ1O)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(acetonitrile)(benzoate-κ1O)]

There total 3 articles about [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(acetonitrile)(benzoate-κ1O)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

dichloromethane (75-09-2) + [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(benzoate-κ2O,O')] (791601-93-9) + acetonitrile (75-05-8,26809-02-9) → [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(acetonitrile)(benzoate-κ1O)] (1068652-98-1)

Guidance literature:

In acetonitrile; (Ar); stirring CH3CN soln. of ruthenium compd. at room temp. for 4 h; IR monitoring, concg., addn. of pentane, filtration, drying in vac., elem. anal.;

DOI:10.1021/ic8000224

Reference yield:

[Ru(bis(3,5-dimethylpyrazol-1-yl)acetate)Cl(PPh3)2] (425370-68-9) → [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(acetonitrile)(benzoate-κ1O)] (1068652-98-1)

Guidance literature:

Multi-step reaction with 2 steps

1: not given

2: acetonitrile

In acetonitrile;

DOI:10.1021/ic8000224

Reference yield:

thallium benzoate (5630-31-9) → [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(acetonitrile)(benzoate-κ1O)] (1068652-98-1)

Guidance literature:

Multi-step reaction with 2 steps

1: not given

2: acetonitrile

In acetonitrile;

DOI:10.1021/ic8000224

upstream raw materials:

dichloromethane

[Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(benzoate-κ2O,O')]

acetonitrile

[Ru(bis(3,5-dimethylpyrazol-1-yl)acetate)Cl(PPh₃)2]

Refernces