[Os(hydride)5(diphenylphosphine)(triisopropylphosphine)2]BF₄

Base Information

• Chemical Name: [Os(hydride)5(diphenylphosphine)(triisopropylphosphine)2]BF₄
• CAS No.: 389575-30-8
• Molecular Formula: BF₄*C₃₀H₅₈OsP₃
• Molecular Weight: 788.716
• Mol file: 389575-30-8.mol

Synonyms:

Chemical Property of [Os(hydride)5(diphenylphosphine)(triisopropylphosphine)2]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Os(hydride)5(diphenylphosphine)(triisopropylphosphine)2]BF₄

There total 1 articles about [Os(hydride)5(diphenylphosphine)(triisopropylphosphine)2]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + Os(hydride)4(diphenylphosphine)(triisopropylphosphine)2 (389575-26-2) → [Os(hydride)5(diphenylphosphine)(triisopropylphosphine)2]BF4 (389575-30-8)

Guidance literature:

In diethyl ether; under Ar; a soln. of the complex in diethyl ether was treated with HBF4*O(CH2CH3)2 for 40 min; the solid was filtered off, washed with diethyl ether and dried in vac.;elem. anal.;

DOI:10.1021/om010173c

Reference yield: 86.0%

[Os(hydride)5(diphenylphosphine)(triisopropylphosphine)2]BF4 (389575-30-8) + diphenylphosphane (829-85-6) → [Os(hydride)3(diphenylphosphine)2(triisopropylphosphine)2]BF4 (389575-32-0)

Guidance literature:

In dichloromethane; byproducts: H2; under Ar; a soln. of the complex in dichloromethane was treated with diphenylphosphine during 1 d at 25°C; the solvent was removed in vac., the residue was washed with diethyl ether; elem. anal.;

DOI:10.1021/om010173c

Reference yield: 74.0%

methanol (67-56-1) + [Os(hydride)5(diphenylphosphine)(triisopropylphosphine)2]BF4 (389575-30-8) → [Os(hydride)3(methoxydiphenylphosphine)(triisopropylphosphine)2]BF4 (389575-34-2)

Guidance literature:

In methanol; byproducts: H2; under Ar; a soln. of the complex in methanol was stirred for 6 d at 25°C; the solvent was removed in vac., the residue was washed with diethyl ether; elem. anal.;

DOI:10.1021/om010173c

upstream raw materials:

tetrafluoroboric acid diethyl ether

Os(hydride)4(diphenylphosphine)(triisopropylphosphine)2

Downstream raw materials:

[Os(hydride)3(diphenylphosphine)2(triisopropylphosphine)2]BF₄

[Os(hydride)3(methoxydiphenylphosphine)(triisopropylphosphine)2]BF₄