(C₆H₅C(O)C(NO)C₆H₅)SbCl₂

Base Information

• Chemical Name: (C₆H₅C(O)C(NO)C₆H₅)SbCl₂
• CAS No.: 200511-66-6
• Molecular Formula: C₁₄H₁₀Cl₂NO₂Sb
• Molecular Weight: 416.895
• Mol file: 200511-66-6.mol

Synonyms:

Chemical Property of (C₆H₅C(O)C(NO)C₆H₅)SbCl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (C₆H₅C(O)C(NO)C₆H₅)SbCl₂

There total 2 articles about (C₆H₅C(O)C(NO)C₆H₅)SbCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

benzilmonoxime (574-15-2,574-16-3,14090-77-8,5351-34-8) + antimony(III) chloride (10025-91-9) → (C6H5C(O)C(NO)C6H5)SbCl2 (200511-66-6)

Guidance literature:

With sodium; isopropyl alcohol; In isopropyl alcohol; benzene; byproducts: NaCl; exclusion of moisture, metal : ligand : Na ratio = 1 : 1 : 1; refluxing (0.5 h) mixt. of reagents, cooling, addn. of ligand, refluxing (2 h), addn. of Sb-salt, refluxing (2 h); solvent evapn. (reduced pressure), filtration, crystn. (benzene/petroleum ether (40 - 60°C)); elem. anal.;

DOI:10.1080/00945719708003155

Reference yield:

benzilmonoxime (574-15-2,574-16-3,14090-77-8,5351-34-8) + antimony(III) chloride (10025-91-9) + sodium (7440-23-5) → (C6H5C(O)C(NO)C6H5)SbCl2 (200511-66-6)

Guidance literature:

In isopropyl alcohol; benzene; byproducts: NaCl; dry N2 atmosphere; addn. of Na to excess of i-PrOH, refluxing (0.5 h), cooling, addn. of oxime, refluxing (2 h), cooling, addn. of stoichiom. amt. of SbCl3 in benzene, refluxing (3 h); sovent removal (reduced pressure), filtration off of NaCl, crystn. (benzene/petroleum ether);

DOI:10.1080/00945719909351729

Reference yield: 94.0%

(C6H5C(O)C(NO)C6H5)SbCl2 (200511-66-6) + potassium O-isobutyl dithiocarbonate (13001-46-2) → (C6H5C(O)C(NO)C6H5)Sb(S2COCH2CH(CH3)2)2 (256460-54-5)

Guidance literature:

In carbon disulfide; benzene; byproducts: KCl; dry N2 atmosphere; addn. of Sb complex in benzene to suspn. of thiocarbonate in benzene/CS2, stirring (3 - 4 h); filtration off of KCl, solvent removal (reduced pressure), recrystn. (benzene/CS2); elem. anal.;

DOI:10.1080/00945719909351729

upstream raw materials:

benzilmonoxime

antimony(III) chloride

sodium

Downstream raw materials:

(C₆H₅C(O)C(NO)C₆H₅)Sb(S₂COCH₂CH(CH₃)2)2