13001-46-2

Usage

Flammability and Explosibility

Highlyflammable

InChI:InChI=1/C5H10OS2/c1-4(2)3-6-5(7)8/h4H,3H2,1-2H3,(H,7,8)

Upstream product

• 75-15-0 carbon disulfide 
• 78-83-1 2-methyl-propan-1-ol 

Downstream Products

• 116429-56-2 O-isobutyl S-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl) dithiocarbonate 
• 116429-61-9 O-isobutyl S-(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl) dithiocarbonate 
• 116429-60-8 O-isobutyl S-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl) dithiocarbonate 
• 116429-57-3 O-isobutyl S-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl) dithiocarbonate 
• 75-15-0 carbon disulfide 
• 78-83-1 2-methyl-propan-1-ol 
• 1861-52-5 O-(2-Methyl-propyl)-S-(4-brom-phenacyl)-dithiocarbonat 
• 93097-83-7 di-O-isobutyl-S,S-phthaloyl dixanthate (symmetrical) 
• 513-44-0 2-methylpropanethiol-1 
• 85863-49-6 bis(iso-butyl xanthato)bis(p-biphenyl)tin(IV) 
• 256460-69-2 (C₆H₅C(NOH)C(NO)C₆H₅)Sb(S₂COCH₂CH(CH₃)2)2 
• 31197-67-8 iso-butyl 2-oxo-2-phenylacetate 

Relevant academic research and scientific papers

Organotin(IV) derivatives of o-isobutyl carbonodithioate: Synthesis, spectroscopic characterization, X-ray structure, HOMO/LUMO and in vitro biological activities

A series of organotin(IV) complexes have been synthesized by reacting potassium o-isobutyl carbonodithioate with di- and triorganotin halides in methanol under stirring conditions. The newly synthesized complexes have been characterized by elemental analysis, FT-IR, NMR (1H and 13C) and X-ray crystallography. The FT-IR results show that the ligand acts as bidentate in complexes 1-3 and monodentate in complexes 4 and 5, which were also confirmed by theoretical calculations. The NMR data reveal four and six coordinated geometries in solution. A HOMO-LUMO study shows that all the complexes are stable. Biological screenings demonstrate that, with a few exceptions, all the complexes show significant activity against various bacterial and fungal strains. The synthesized complexes were also found to be effective antioxidants of the 2,2-diphenyl-1-picrylhydrazyl radical (DPPH). All the complexes have been assayed for antileishmanial activity in vitro and found some promising results. The UV-Vis studies confirmed that the ligand and its complexes bind to DNA via intercalative interactions, resulting in hypochromism and minor red shifts.

Accessing γ-Ga2S3 by solventless thermolysis of gallium xanthates: A low-temperature limit for crystalline products

Alkyl-xanthato gallium(iii) complexes of the form [Ga(S2COR)3], where R = Me (1), Et (2), iPr (3), nPr (4), nBu (5), sBu (6) and iBu (7), have been synthesized and fully characterised. The crystal structures for 1 and 3-7 have been solved and examined to elucidate if these structures are related to their decomposition. Thermogravimetric analysis was used to gain insight into the decomposition temperatures for each complex. Unlike previously explored metal xanthate complexes which break down at low temperatures (2S3 was the sole product formed. In the case of R = Me, Chugaev elimination did not occur and amorphous GaxSy products were formed. We conclude therefore that the low-temperature synthesis route offered by the thermal decomposition of metal xanthate precursors, which has been reported for many metal sulfide systems prior to this, may not be appropriate in the case of gallium sulfides.

Novel Xanthate Complexes for the Size-Controlled Synthesis of Copper Sulfide Nanorods

We present a simple, easily scalable route to monodisperse copper sulfide nanocrystals by the hot injection of a series of novel copper(I) xanthate single-source precursors [(PPh3)2Cu(S2COR)] (R = isobutyl, 2-methoxyethyl, 2-ethoxyethyl, 1-methoxy-2-propyl, 3-methoxy-1-butyl, and 3-methoxy-3-methyl-1-butyl), whose crystal structures are also reported. We show that the width of the obtained rods is dependent on the length of the xanthate chain, which we rationalize through a computational study, where we show that there is a relationship between the ground-state energy of the precursor and the copper sulfide rod width.

Synthesis and characterization of various xanthates and their effects on germination and early seedling growth in wheat (Triticum aestivum L.)

Potassium n-propyl xanthate potassium iso-propyl xanthate, potassium n-butyl xanthate and potassium iso-butyl xanthate were synthesized and characterized by melting point, elemental analysis and infrared spectra and their effect on germination and early seedling growth in wheat (Triticum aestivum L.) were studied. All chemical treatments decreased per cent germination length and dry weight of shoots decreased at all concentrations except at 5 and 10 ppm n-propyl xanthate. Root length also decreased except at 5,10 and 25 ppm of potassium iso-propyl xanthate and potassium iso-butyl xanthate, root dry weight decreased with all chemical treatments except at 5 and 10 ppm in case of potassium n-butyl xanthate.

Water-soluble three qinqin amines benzene sulfonic acid alkali metal salt derivative and its preparation method and application

The invention discloses a water soluble triazine amino benzene sulfonic acid alkali metal salt derivative and a preparation method and application thereof. The invention relates to a synthesis process and application of an amino benzene sulfonic acid sodium and xanthonic acid group-containing triazine derivative, and is characterized in that: the 2-alkyl xanthate-4, 6-diamino benzene sulfonic acid alkali metal salt-1,3,5-s-triazine has the following structural formula shown in the specification, wherein X is Na, R is C1-C4 straight chain or branched chain alkyl. The preparation method is as follows: using cyanuric chloride, amino benzene sulfonic acid and potassium alkyl xanthate with the molar ratio of 1: 1.1: 2-2.1 as raw materials for reaction in an organic solvent. The amino benzene sulfonic acid sodium-containing triazine derivative can be used as additives used in pure water, water-glycol, synthetic ester, lithium base grease or calcium base grease, and by compounding with other water-based lubricant additives, the water soluble triazine amino benzene sulfonic acid alkali metal salt derivative has good abrasion resistance, extreme pressure resistance, corrosion resistance, and oxidation resistance. The synthesis process has the advantages of simple operation, high yield, and easy control of reaction condition.

Water-soluble triazine xanthogen derivative and its preparation method and application

The invention discloses a water-soluble triazine xanthic acid derivative, and a preparation method and application thereof. The invention relates to a synthetic technology and application of a water-soluble triazine derivative containing a xanthic acid group. The derivative is characterized in that the derivative has the chemical name of 2,4-bis(N,N-dihydroxyalkylamino)-6-(alkylxanthate)-1,3,5-sym-triazine, and has the structural formula shown in the specification, and in the structural formula, R1 is a C1-C2 linear or branched alkyl, and R is a C1-C5 linear or branched alkyl. The preparation method of the derivative comprises utilizing cyanuric chloride, a dialkyl alcohol amine and an alkyl xanthate as raw materials, controlling the reaction molar ratio to be 1:2:1.1, taking an alcohol as a solvent, and reacting at 60-90 DEG C for 4-6 h. The derivative can be applied to pure water, water-glycol, water-glycerin, synthetic esters, polyesters and lubricating grease as an additive, also can be combined with other aqueous lubricating additives for usage, and has good wear resistance and extreme pressure resistance, and capabilities of resisting corrosion and resisting oxidation. The method is simple in operation, high in yield and easily controllable in reaction conditions.

Process for the preparation of thiocarbamic acid O-esters

Process for the preparation of thiocarbamic acid-O-esters of the general formula EQU1 in which R1 means an alkyl or cycloalkyl radical, R2 and R3 each stands for an alkyl radical which may be substituted by one of the groups --(O--C2 H4)n --OH, --(OC2 H4)n --OCH3 or --O--(CH2)m --CH3, n being 0, 1 or 2 and m being 1 or 2, or stand for a cycloalkyl radical, and one of the radicals R2 and R3 may be hydrogen which process comprises reacting at a temperature ranging between 20° and 120°C in an aqueous or water-containing medium a xanthogenate of the formula EQU2 in which R1 is defined as above and Me is an alkali metal with a primary or secondary aliphatic amine of the formula EQU3 in which R2 and R3 are defined as above, and elementary sulfur.