Rh(C₁₃H₈N)Br₂(P(C₆H₅)3)2

Base Information

• Chemical Name: Rh(C₁₃H₈N)Br₂(P(C₆H₅)3)2
• CAS No.: 1103534-59-3
• Molecular Formula: C₄₉H₃₈Br₂NP₂Rh
• Molecular Weight: 965.508
• Mol file: 1103534-59-3.mol

Synonyms:

Chemical Property of Rh(C₁₃H₈N)Br₂(P(C₆H₅)3)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Rh(C₁₃H₈N)Br₂(P(C₆H₅)3)2

There total 2 articles about Rh(C₁₃H₈N)Br₂(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

10-bromobenzoquinoline (152583-10-3) + [Rh(I)(norbornadiene)(PPh3)2]PF6 (32799-32-9) + hydrogen (1333-74-0) + acetone (67-64-1) → Rh(C13H8N)Br2(P(C6H5)3)2 (1103534-59-3)

Guidance literature:

With tert-butylethylene; In acetone; (Schlenk); bubbling H2 through a suspn. of Rh complex in acetone for 15 min at 0°C, addn. of tert-butylethylene and 2 equivs. of ligand, reflux for 10 h; filtration, washing ppt. with acetone, cold CH2Cl2, OEt2, elem. anal.;

DOI:10.1021/ic801878e

Reference yield:

[RhBr(C13H8N)(P(C6H5)3)2](1+)*PF6(1-)=[RhBr(C13H8N)(P(C6H5)3)2]PF6 (1103534-54-8) + acetone (67-64-1) → Rh(C13H8N)(P(C6H5)3)2(CH3COCH3)(2+) + Rh(C13H8N)Br2(P(C6H5)3)2 (1103534-59-3)

Guidance literature:

In acetone; (Schlenk); heating acetone suspension of Rh complex, yield about 40%;

DOI:10.1021/ic801878e

upstream raw materials:

10-bromobenzoquinoline

[Rh(I)(norbornadiene)(PPh₃)2]PF₆

hydrogen

acetone