(2,6-i-Pr₂C₆H₃N)2MoMe₂

Base Information

• Chemical Name: (2,6-i-Pr₂C₆H₃N)2MoMe₂
• CAS No.: 214285-72-0
• Molecular Formula: C₂₆H₄₀MoN₂
• Molecular Weight: 476.557
• Mol file: 214285-72-0.mol

Synonyms:

Chemical Property of (2,6-i-Pr₂C₆H₃N)2MoMe₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,6-i-Pr₂C₆H₃N)2MoMe₂

There total 4 articles about (2,6-i-Pr₂C₆H₃N)2MoMe₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

MoCl2(N(2,6-i-Pr2C6H3))2(1,2-dimethoxyethane) + methylmagnesium bromide (75-16-1) → (2,6-i-Pr2C6H3N)2MoMe2 (214285-72-0)

Guidance literature:

In diethyl ether; (N2); slow addn. of MemgBr in Et2O to a soln. of Mo complex in Et2O at -78°C, slow warming to ambient temp., stirring (12 h); filtration, extraction (Et2O, then pentane), removal of volatiles, extraction into pentane, cooling to -78°C; elem. anal.;

Reference yield:

MoCl2(N(2,6-i-Pr2C6H3))2(1,2-dimethoxyethane) + methylmagnesium chloride (676-58-4) → (2,6-i-Pr2C6H3N)2MoMe2 (214285-72-0)

Guidance literature:

In not given;

DOI:10.1039/a803221a

Reference yield:

[MoMe2(N(2,6-Pr2(i)-C6H3)AlMe2(μ-Cl))(N-2,6-Pr2(i)-C6H3)] (1373886-46-4) → (2,6-i-Pr2C6H3N)2MoMe2 (214285-72-0)

Guidance literature:

With NEt₃; In benzene-d6; under N2; by a react. of Mo-contg. compd. (0.07 mmol) in C6D6 with NEt3 (0.35 mmol); warming to room temp.; (1)H NMR spectra monitoring;

DOI:10.1039/c2dt12061e

upstream raw materials:

methylmagnesium bromide

methylmagnesium chloride

methylaluminum dichloride

[MoMe2(N(2,6-Pr2(i)-C6H3)AlMe2(μ-Cl))(N-2,6-Pr2(i)-C6H3)]

Downstream raw materials:

[MoMe2(N(2,6-Pr2(i)-C6H3)AlMe2(μ-Cl))(N-2,6-Pr2(i)-C6H3)]

[Mo(CH₃)(NC₆H₃(CH(CH₃)2)2)2]2(OCH₃)2

Mo(CH₃)2(C₅H₅N)(NC₆H₃(CH(CH₃)2)2)2

Mo(CH₃)2(C₄H₈O)(NC₆H₃(CH(CH₃)2)2)2