Phenol, 2-(2E)-2-butenyl-

Base Information

• Chemical Name: Phenol, 2-(2E)-2-butenyl-
• CAS No.: 14004-15-0
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol file: 14004-15-0.mol

Synonyms:

Chemical Property of Phenol, 2-(2E)-2-butenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenol, 2-(2E)-2-butenyl-

There total 20 articles about Phenol, 2-(2E)-2-butenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

1-chloro-2-butene (591-97-9) + phenol (108-95-2,27073-41-2) → 2-crotylphenol (14004-15-0)

Guidance literature:

phenol; With sodium hydride; In benzene; at 0 ℃;

1-chloro-2-butene; In benzene; at 23 ℃; for 12h;

DOI:10.1021/ja055534k

Reference yield:

(E)-(but-2-en-1-yloxy)benzene (14309-16-1) → 2-crotylphenol (14004-15-0) + 2-(but-3-en-2-yl)phenol (18272-63-4)

Guidance literature:

With Montmorillonite KSF clay; In benzene; for 72h; Yield given. Yields of byproduct given; Ambient temperature;

DOI:10.1016/S0040-4039(00)89033-4

Reference yield:

buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) + phenol (108-95-2,27073-41-2) → 2-crotylphenol (14004-15-0)

Guidance literature:

With boron trifluoride; dihydrogen phosphate;

DOI:10.1021/ja01580a016

upstream raw materials:

diphenylether

(but-3-en-2-yloxy)benzene

buta-1,3-diene

phenol

Downstream raw materials:

2-but-1-enyl-phenol

(2-but-2t-enyl-phenoxy)-acetic acid

(E)-1-(2-butenyl)-2-methoxybenzene

2-ethylbenzofuran

Refernces

• 1、 Trend, Raissa M.,Ramtohul, Yeeman K.,Stoltz, Brian M.. "Oxidative cyclizations in a nonpolar solvent using molecular oxygen and studies on the stereochemistry of oxypalladation". . p. 17778 - 17788. Retrieved 2007/10/03.
• 2、 Lim, Hwan Jung,Keum, Gyochang,Kang, Soon Bang,Kim, Youseung,Chung, Bong Young. "A new direct allylation of the aromatic compounds with allylic chlorides catalyzed by indium metal". . p. 1547 - 1550. Retrieved 2007/10/03.