1,2,3,4,5-pentamethylcyclopentadienyliridium(III) chloride bis(2,4,6-trimethylphenylimino)acenapthene tetrafluoroborate - water-dichloromethane - methanol (1/1/1/1)

Base Information

• Chemical Name: 1,2,3,4,5-pentamethylcyclopentadienyliridium(III) chloride bis(2,4,6-trimethylphenylimino)acenapthene tetrafluoroborate - water-dichloromethane - methanol (1/1/1/1)
• CAS No.: 1000700-19-5
• Molecular Formula: BF₄*CH₂Cl₂*CH₄O*C₄₀H₄₃ClIrN₂*H₂O
• Molecular Weight: 1001.26
• Mol file: 1000700-19-5.mol

Synonyms:

Chemical Property of 1,2,3,4,5-pentamethylcyclopentadienyliridium(III) chloride bis(2,4,6-trimethylphenylimino)acenapthene tetrafluoroborate - water-dichloromethane - methanol (1/1/1/1)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2,3,4,5-pentamethylcyclopentadienyliridium(III) chloride bis(2,4,6-trimethylphenylimino)acenapthene tetrafluoroborate - water-dichloromethane - methanol (1/1/1/1)

There total 1 articles about 1,2,3,4,5-pentamethylcyclopentadienyliridium(III) chloride bis(2,4,6-trimethylphenylimino)acenapthene tetrafluoroborate - water-dichloromethane - methanol (1/1/1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

methanol (67-56-1) + sodium tetrafluoroborate (13755-29-8) + bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] (12354-84-6,12354-85-7) + bis[N-(2,4,6-trimethylphenyl)imino]acenaphthene + dichloromethane (75-09-2) → 1,2,3,4,5-pentamethylcyclopentadienyliridium(III) chloride bis(2,4,6-trimethylphenylimino)acenapthene tetrafluoroborate - water-dichloromethane - methanol (1/1/1/1) (1000700-19-5)

Guidance literature:

In methanol; toluene; further educts; (inert atm.), suspn. of Ir complex in toluene stirred for 30 min, treated with 2 equiv. of ligand in toluene, stirred for 30 min, treated dropwise with 2 equiv. of NaBF4 in CH3OH/toluene (1:4), stirred overnight; concd.(vac.), recrystd.(CH2Cl2/pentane), collected, washed (pentane), dried, elem. anal.;

DOI:10.1002/ejic.200600735

upstream raw materials:

methanol

sodium tetrafluoroborate

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

dichloromethane