[(η5-cyclopentadienyl)Ru(triphenylphosphine)2(C(OMe)CH2(uracyl))]OTf*toluene

Base Information

• Chemical Name: [(η5-cyclopentadienyl)Ru(triphenylphosphine)2(C(OMe)CH2(uracyl))]OTf*toluene
• CAS No.: 1201797-42-3
• Molecular Formula: CF₃O₃S*C₇H₈*C₄₈H₄₃N₂O₃P₂Ru
• Molecular Weight: 1100.11
• Mol file: 1201797-42-3.mol

Synonyms:

Chemical Property of [(η5-cyclopentadienyl)Ru(triphenylphosphine)2(C(OMe)CH2(uracyl))]OTf*toluene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-cyclopentadienyl)Ru(triphenylphosphine)2(C(OMe)CH2(uracyl))]OTf*toluene

There total 1 articles about [(η5-cyclopentadienyl)Ru(triphenylphosphine)2(C(OMe)CH2(uracyl))]OTf*toluene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + ammonium triflate (38542-94-8) + toluene (108-88-3,15644-74-3,16713-13-6) + 5-ethynyluracil (59989-18-3) → [(η5-cyclopentadienyl)Ru(triphenylphosphine)2(C(OMe)CH2(uracyl))]OTf*toluene (1201797-42-3) + [(η5-cyclopentadienyl)Ru(triphenylphosphine)2(E-CHC(PPh3)(uracyl))]OTf (1201797-30-9)

Guidance literature:

In methanol; byproducts: NH4Cl; (inert atm.); heating mixt. of ruthenium compd., uracyl deriv. and NH4PF6 in methanol at reflux for 16 h; cooling to room temp., filtration, concg., addn. of toluene, isolation of crystals, NMR and MS;

DOI:10.1039/b912855g

upstream raw materials:

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

ammonium triflate

toluene

5-ethynyluracil