Mn(CO)2((C₆H₅)2P(CH₂)2)3PCl

Base Information

• Chemical Name: Mn(CO)2((C₆H₅)2P(CH₂)2)3PCl
• CAS No.: 308820-56-6
• Molecular Formula: C₄₄H₄₂ClMnO₂P₄
• Molecular Weight: 817.102
• Mol file: 308820-56-6.mol

Synonyms:

Chemical Property of Mn(CO)2((C₆H₅)2P(CH₂)2)3PCl

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of Mn(CO)2((C₆H₅)2P(CH₂)2)3PCl

There total 1 articles about Mn(CO)2((C₆H₅)2P(CH₂)2)3PCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pentacarbonylchloromanganese(I) (14100-30-2) + tris(2-diphenylphosphinoethyl)phosphine (23582-03-8) → Mn(CO)2((C6H5)2P(CH2)2)3PCl (308820-55-5,308820-56-6,309718-94-3) + Mn(CO)2((C6H5)2P(CH2)2)3P(1+)*Cl(1-)*CHCl3=Mn(CO)2((C6H5)2P(CH2)2)3PCl*CHCl3

Guidance literature:

In xylene; Mn-complex and ligand were reacted in refluxing xylene for 2 h under N2; cooled, filtered, dissolved in CH2Cl2; elem. anal.;

DOI:10.1021/ic0000294

Reference yield:

potassium hexafluorophosphate (17084-13-8) + Mn(CO)2((C6H5)2P(CH2)2)3PCl (308820-55-5,308820-56-6,309718-94-3) + methyl iodide (74-88-4) → Mn(CO)2((C6H5)2P(CH2)2)3PCH3Cl(1+)*PF6(1-)=Mn(CO)2((C6H5)2P(CH2)2)3PCH3ClPF6 (308820-59-9)

Guidance literature:

In dichloromethane; MeI was added to Mn-complex in CH2Cl2 under N2; soln. was evapd., acetone soln. was passed through exchange column withKPF6;

DOI:10.1021/ic0000294

upstream raw materials:

pentacarbonylchloromanganese(I)

tris(2-diphenylphosphinoethyl)phosphine

Downstream raw materials:

Mn(CO)2((C₆H₅)2P(CH₂)2)3PCH₃Cl⁽¹⁺⁾*PF₆^(1-)=Mn(CO)2((C₆H₅)2P(CH₂)2)3PCH₃ClPF₆