S-Ethyl thiobenzoate

Base Information

• Chemical Name: S-Ethyl thiobenzoate
• CAS No.: 1484-17-9
• Molecular Formula: C9H10OS
• Molecular Weight: 166.244
• Hs Code.: 2930909090
• Mol file: 1484-17-9.mol

Synonyms:Benzoic acid,thio-,S-ethyl ester;thiobenzoic S-ethyl ester;S-ethyl benzothioate;S-ethyl thiobenzoate;Ethyl thiobenzoate;Benzenecarbothioic acid,S-ethyl ester;Thiobenzoic acid S-ethyl ester;

Chemical Property of S-Ethyl thiobenzoate

Chemical Property:

• PSA: 42.37000
• LogP: 2.57990

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of S-Ethyl thiobenzoate

There total 64 articles about S-Ethyl thiobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(ethylthio)trimethylsilane (5573-62-6) + benzoyl chloride (98-88-4) → S-ethyl thiobenzoate (1484-17-9)

Guidance literature:

With perhydrodibenzo-18-crown-6; potassium fluoride; In dichloromethane; for 6h; Ambient temperature;

DOI:10.1246/cl.1982.885

Reference yield: 95.0%

benzoyl chloride (98-88-4) + ethanethiol (75-08-1) → S-ethyl thiobenzoate (1484-17-9)

Guidance literature:

With pyridine; for 24h;

DOI:10.1021/jo00095a047

Reference yield: 94.0%

vinyl benzoate (769-78-8,24991-32-0) + ethanethiol (75-08-1) → S-ethyl thiobenzoate (1484-17-9)

Guidance literature:

With potassium carbonate; In acetonitrile; at 20 ℃;

DOI:10.1002/adsc.201800914

upstream raw materials:

ethyl bromide

thiobenzoic acid

benzoyl chloride

ethanethiol

Downstream raw materials:

3-phenylpentan-3-ol

triphenylmethyl alcohol

ethanethiol

1-(ethylthio)-2-methyl-1-phenyl-1-propene

Refernces

• 1、 Lu, Kui,Lv, Ming-Xiu,Mai, Wen-Peng,Sui, Hong-Da. "Nickel-catalyzed carbonylation of thioacetates with aryl iodides via CO insertion and C–S bond cleavage". . p. 890 - 895. Retrieved 2021/07/02.
• 2、 Steemers, Luuk,Wijsman, Linda,van Maarseveen, Jan H.. "Regio- and Stereoselective Chan-Lam-Evans Enol Esterification of Carboxylic Acids with Alkenylboroxines". supporting information. p. 4241 - 4245. Retrieved 2018/10/02.