1-Chloro-1,1-dimethyl-N,N-bis(trimethylsilyl)silanamine

Base Information

• Chemical Name: 1-Chloro-1,1-dimethyl-N,N-bis(trimethylsilyl)silanamine
• CAS No.: 1586-72-7
• Molecular Formula: C8H24ClNSi3
• Molecular Weight: 253.995
• European Community (EC) Number: 827-001-6
• DSSTox Substance ID: DTXSID90579634
• Wikidata: Q82470227
• Mol file: 1586-72-7.mol

Synonyms:1586-72-7;1-Chloro-1,1-dimethyl-N,N-bis(trimethylsilyl)silanamine;Silanamine, N-(chlorodimethylsilyl)-1,1,1-trimethyl-N-(trimethylsilyl)-;DTXSID90579634;[[[chloro(dimethyl)silyl]-trimethylsilylamino]-dimethylsilyl]methane

Chemical Property of 1-Chloro-1,1-dimethyl-N,N-bis(trimethylsilyl)silanamine

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 253.0905071
• Heavy Atom Count: 13
• Complexity: 167

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)N([Si](C)(C)C)[Si](C)(C)Cl

Technology Process of 1-Chloro-1,1-dimethyl-N,N-bis(trimethylsilyl)silanamine

There total 2 articles about 1-Chloro-1,1-dimethyl-N,N-bis(trimethylsilyl)silanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

tris(trimethylsilyl)amine (1586-73-8) + boron trichloride (10294-34-5) → chloro-trimethyl-silane (75-77-4) + dichloro-methyl-borane (7318-78-7) + N-(chlorodimethylsilyl)-N,N-bis(trimethylsilyl)amine (1586-72-7) + Bis(chlordimethylsilyl)(trimethylsilyl)amin (18790-09-5)

Guidance literature:

React. of starting materials (vac., 150°C, 16 h).; Sepn. of volatile materials (9.5% unreacted BCl3, Me3SiCl, MeBCl2) by fractional condensation. Identification by mass spectroscopy.;

Reference yield:

tris(trimethylsilyl)amine (1586-73-8) + boron trichloride (10294-34-5) → chloro-trimethyl-silane (75-77-4) + N-(chlorodimethylsilyl)-N,N-bis(trimethylsilyl)amine (1586-72-7) + Bis(chlordimethylsilyl)(trimethylsilyl)amin (18790-09-5) + bis(trimethylsilyl)aminodichloroborane (6591-26-0)

Guidance literature:

React. of starting materials (vac., room temp., 20 h).; Sepn. of volatile materials by fractional condensation. Identification by mass spectroscopy.;

Reference yield:

N-(chlorodimethylsilyl)-N,N-bis(trimethylsilyl)amine (1586-72-7) + 4-Vinylbenzyl chloride (1592-20-7,29296-32-0) → N-(dimethyl(4-vinylphenyl)silyl)-N,N-bis(trimethylsilyl)amine

Guidance literature:

With iodine; magnesium; In tetrahydrofuran; at 25 - 40 ℃; for 11h; Reagent/catalyst; Inert atmosphere;

upstream raw materials:

tris(trimethylsilyl)amine

boron trichloride