1,3-Dimethyl-2-(trimethylsilyloxy)benzene

Base Information

• Chemical Name: 1,3-Dimethyl-2-(trimethylsilyloxy)benzene
• CAS No.: 16286-54-7
• Molecular Formula: C11H18OSi
• Molecular Weight: 194.349
• Hs Code.: 2931900090
• Mol file: 16286-54-7.mol

Synonyms:1,3-Dimethyl-2-(trimethylsilyloxy)benzene;2,6-dimethylphenyltrimethylsilylether;2,6-dimethylphenoxy(trimethyl)silan;2,6-dimethylphenoxy(trimethyl)silane;Me3Si(2,6-dimethylphenoxide);Silane,trimethyl(2,6-xylyloxy);Silane,(2,6-dimethylphenoxy)trimethyl;

Chemical Property of 1,3-Dimethyl-2-(trimethylsilyloxy)benzene

Chemical Property:

• PSA: 9.23000
• LogP: 3.51710

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-Dimethyl-2-(trimethylsilyloxy)benzene

There total 11 articles about 1,3-Dimethyl-2-(trimethylsilyloxy)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2.6-dimethylphenol (576-26-1,25134-01-4) + allyl-trimethyl-silane (762-72-1) → 1,3-dimethyl-2-trimethylsilyloxybenzene (16286-54-7)

Guidance literature:

Nafion-H; In tetrachloromethane; for 1h; Heating;

DOI:10.1055/s-1983-30553

Reference yield: 96.0%

trimethylsilylazide (4648-54-8) + (2,6-(Me2NCH2)2C6H3)Bi(OC6H3Me2-2,6)2 (1283161-00-1) → 1,3-dimethyl-2-trimethylsilyloxybenzene (16286-54-7) + C12H19BiN8 (1433927-52-6)

Guidance literature:

In tetrahydrofuran; for 1h; Inert atmosphere;

DOI:10.1021/ja403133f

Reference yield: 93.0%

2.6-dimethylphenol (576-26-1,25134-01-4) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → 1,3-dimethyl-2-trimethylsilyloxybenzene (16286-54-7)

Guidance literature:

With lanthanum(III) chloride; In dichloromethane; at 20 ℃; for 3.5h;

DOI:10.1016/j.jorganchem.2007.05.002

upstream raw materials:

2.6-dimethylphenol

N,N-bis(trimethylsilyl)acetamide

chloro-trimethyl-silane

Trimethylsilanol

Downstream raw materials:

trans-{Ta(2,6-dimethylphenoxide)Cl₄(diethyl ether)}

ZrCl₂{O-2,6-(CH₃)2C₆H₃}2(THF)2

ZrCl₃{O-2,6-(CH₃)2C₆H₃}(THF)2

NbCl₃{O-2,6-(CH₃)2C₆H₃}2(THF)